Author, as appears in the article.: Margalef J; Pàmies O; Pericàs MA; Diéguez M

Department: Química Física i Inorgànica

URV's Author/s: Diéguez Fernández, Montserrat / Pamies Ollé, Oscar

Keywords: Planar chiral ligands Phosphite-oxazoline ligands Minimally functionalized olefins Mannich reaction Glycine imino ester Diels-alder reaction Cyclic beta-enamides Azomethine ylides Allylic alkylation 1,3-dipolar cycloaddition

Abstract: © The Royal Society of Chemistry 2020. In the early 1990s chiral P-thiother ligands emerged as promising ligands in the field of asymmetric catalysis, with the development of many P-thioether ligand families. However, only a few of them have shown a broad reaction and substrate scope. So, compared with other heterodonor ligands such as the widely studied P-N ligands, their impact in asymmetric catalysis was not realised until recently. This has been mainly attributed to the difficulty of controlling the configuration at the sulfur atom when coordinated to the metal. More recently, it has been found that this problem could be solved by a rigorous choice of the ligand scaffold, a process usually aided by mechanistic studies. This allowed the recent discovery of new P-thioether ligand families with a broader versatility, both in reactions and in substrate/reagent scope. This feature article aims to highlight those new P-thioether ligand libraries and the relationship between the structure and catalytic performance.

Thematic Areas: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física

licence for use: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 13597345

Author's mail: montserrat.dieguez@urv.cat oscar.pamies@urv.cat

Author identifier: 0000-0002-8450-0656 0000-0002-2352-8508

Record's date: 2023-02-19

Papper version: info:eu-repo/semantics/submittedVersion

Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2020/cc/d0cc04145a

Licence document URL: http://repositori.urv.cat/ca/proteccio-de-dades/

Papper original source: Chemical Communications. 56 (74): 10795-10808

APA: Margalef J; Pàmies O; Pericàs MA; Diéguez M (2020). Evolution of phosphorus-thioether ligands for asymmetric catalysis. Chemical Communications, 56(74), 10795-10808. DOI: 10.1039/d0cc04145a

Article's DOI: 10.1039/d0cc04145a

Entity: Universitat Rovira i Virgili

Journal publication year: 2020

Publication Type: Journal Publications