Articles producció científicaQuímica Analítica i Química Orgànica

Assembly of Complex 1

  • Identification data

    Identifier:  imarina:9093095
    Handle: https://hdl.handle.net/20.500.11797/imarina9093095
    Authors:  Armengol-Relats, Helena; Mato, Mauro; Echavarren, Antonio M
    Abstract:
    The formal (4+3) cycloaddition of 1,3-dienes with Rh(II) and Au(I) non-acceptor vinyl carbenes, generated from vinylcycloheptatrienes or alkoxyenynes, respectively, leads to 1,4-cycloheptadienes featuring complex and diverse substitution patterns, including natural dyctiopterene C ' and a hydroxylated derivative of carota-1,4-diene. A complete mechanistic picture is presented, in which Au(I) and Rh(II) non-acceptor vinyl carbenes were shown to undergo a vinylcyclopropanation/Cope rearrangement or a direct (4+3) cycloaddition that takes place in a non-concerted manner.

  • Others:

    Link to the original source: https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202012092
    APA: Armengol-Relats, Helena; Mato, Mauro; Echavarren, Antonio M (2021). Assembly of Complex 1,4-Cycloheptadienes by (4+3) Cycloaddition of Rhodium(II) and Gold(I) Non-Acceptor Carbenes. Angewandte Chemie (International Ed. Print), 60(4), 1916-1922. DOI: 10.1002/anie.202012092
    Paper original source: Angewandte Chemie (International Ed. Print). 60 (4): 1916-1922
    Article's DOI: 10.1002/anie.202012092
    Journal publication year: 2021
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2025-02-18
    URV's Author/s: Armengol Relats, Helena / ECHAVARREN PABLOS, ANTONIO / Mato Gómez, Mauro
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    ISSN: 0044-8249
    Author, as appears in the article.: Armengol-Relats, Helena; Mato, Mauro; Echavarren, Antonio M
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    e-ISSN: 1521-3757
    Thematic Areas: Química, Medicina ii, Medicina i, Materiais, Interdisciplinar, General medicine, General chemistry, Farmacia, Engenharias ii, Ciências biológicas iii, Ciências biológicas ii, Ciências biológicas i, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Chemistry, Catalysis, Astronomia / física
    Author's mail: antoniomaria.echavarren@urv.cat, helena.armengol@estudiants.urv.cat

  • Keywords:

    Retro-buchner reaction
    Metal carbenes
    Hydrocarbons
    H functionalization
    Enyne cycloisomerizations
    Dienediynes
    Decarbenation reactions
    Cyclopropanes
    Cyclopropanation/cope rearrangement
    Cycloheptadienes
    Cycloadditions
    Cyclization
    Construction
    Catalyzed cycloisomerization
    Access
    Catalysis
    Chemistry
    Chemistry (Miscellaneous)
    Multidisciplinary
    Química
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Chemistry (all)
    Astronomia / física

  • Documents:

    DocumentPrincipal

  • Cerca a google

    Search to google scholar