Author, as appears in the article.: Souleymanou, Myriam Y.; El-Ouahabi, Fatima; Masdeu-Bulto, Anna M.; Godard, Cyril;
Department: Química Física i Inorgànica
e-ISSN: 1867-3899
URV's Author/s: Godard, Cyril / Masdeu Bultó, Anna Maria / SOULEYMANOU, MYRIAM YASMINE
Project code: CTQ2016-75016-R
Keywords: Sustainable conversion Supported organocatalyst Reduced graphene oxides (rgo) Reduced graphene oxide Recoverability Organocatalysts Organic carbonates Nanotubes N-heterocyclic carbenes Metal-complexes Interactions Imidazolium salt Imidazolium carboxylates Heterogeneous catalysis Graphene oxide Graphene Dioxide Cycloaddition reaction Cycloaddition Cyclic carbonates Catalytic system Catalysts Carboxylation Carbon nanotubes Carbon materials Carbon material Carbon dioxide conversion Carbon dioxide Carbon beads Aromatic-compounds π ? interactions
Abstract: New pyrene-tagged imidazolium salts and their corresponding carboxylates were synthesised and the latter tested as organocatalysts in the cycloaddition of CO2 with epoxides. The best performing organocatalyst was then non-covalently immobilised onto carbon materials (carbon nanotubes (CNTs), reduced graphene oxide (rGO) and carbon beads (CBs)) via pi-pi stacking interactions and their activity and recoverability in the cycloaddition reaction were studied. The heterogenised catalyst onto reduced graphene oxide (4 a@rGO) was recycled several times although a loss of activity was observed. This catalyst was also used for the transformation of a series of epoxides under mild conditions.
Thematic Areas: Química Physical and theoretical chemistry Organic chemistry Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências biológicas ii Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, physical Catalysis Biotecnología Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1867-3880
Author's mail: cyril.godard@urv.cat annamaria.masdeu@urv.cat
Author identifier: 0000-0001-5762-4904 0000-0001-7938-3902
Record's date: 2024-07-27
Papper version: info:eu-repo/semantics/acceptedVersion
Funding program: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Chemcatchem. 13 (7): 1706-1710
APA: Souleymanou, Myriam Y.; El-Ouahabi, Fatima; Masdeu-Bulto, Anna M.; Godard, Cyril; (2021). Cooperative NHC-based Catalytic System Immobilised onto Carbon Materials for the Cycloaddition of CO2 to Epoxides. Chemcatchem, 13(7), 1706-1710. DOI: 10.1002/cctc.202001816
Acronym: ECO2VALCAT
Entity: Universitat Rovira i Virgili
Journal publication year: 2021
Funding program action: VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS
Publication Type: Journal Publications
Repositori URV