Articles producció científica> Química Física i Inorgànica

Cooperative NHC-based Catalytic System Immobilised onto Carbon Materials for the Cycloaddition of CO2 to Epoxides

  • Identification data

    Identifier: imarina:9173257
    Authors:
    Souleymanou, Myriam Y.El-Ouahabi, FatimaMasdeu-Bulto, Anna M.Godard, Cyril
    Abstract:
    New pyrene-tagged imidazolium salts and their corresponding carboxylates were synthesised and the latter tested as organocatalysts in the cycloaddition of CO2 with epoxides. The best performing organocatalyst was then non-covalently immobilised onto carbon materials (carbon nanotubes (CNTs), reduced graphene oxide (rGO) and carbon beads (CBs)) via pi-pi stacking interactions and their activity and recoverability in the cycloaddition reaction were studied. The heterogenised catalyst onto reduced graphene oxide (4 a@rGO) was recycled several times although a loss of activity was observed. This catalyst was also used for the transformation of a series of epoxides under mild conditions.
  • Others:

    e-ISSN: 1867-3899
    Project code: CTQ2016-75016-R
    Keywords: Sustainable conversion Supported organocatalyst Reduced graphene oxides (rgo) Reduced graphene oxide Recoverability Organocatalysts Organic carbonates Nanotubes N-heterocyclic carbenes Metal-complexes Interactions Imidazolium salt Imidazolium carboxylates Heterogeneous catalysis Graphene oxide Graphene Dioxide Cycloaddition reaction Cycloaddition Cyclic carbonates Catalytic system Catalysts Carboxylation Carbon nanotubes Carbon materials Carbon material Carbon dioxide conversion Carbon dioxide Carbon beads Aromatic-compounds π ? interactions
    Record's date: 2024-07-27
    Papper version: info:eu-repo/semantics/acceptedVersion
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Chemcatchem. 13 (7): 1706-1710
    APA: Souleymanou, Myriam Y.; El-Ouahabi, Fatima; Masdeu-Bulto, Anna M.; Godard, Cyril; (2021). Cooperative NHC-based Catalytic System Immobilised onto Carbon Materials for the Cycloaddition of CO2 to Epoxides. Chemcatchem, 13(7), 1706-1710. DOI: 10.1002/cctc.202001816
    Acronym: ECO2VALCAT
    Publication Type: Journal Publications
    Author, as appears in the article.: Souleymanou, Myriam Y.; El-Ouahabi, Fatima; Masdeu-Bulto, Anna M.; Godard, Cyril;
    Department: Química Física i Inorgànica
    URV's Author/s: Godard, Cyril / Masdeu Bultó, Anna Maria / SOULEYMANOU, MYRIAM YASMINE
    Abstract: New pyrene-tagged imidazolium salts and their corresponding carboxylates were synthesised and the latter tested as organocatalysts in the cycloaddition of CO2 with epoxides. The best performing organocatalyst was then non-covalently immobilised onto carbon materials (carbon nanotubes (CNTs), reduced graphene oxide (rGO) and carbon beads (CBs)) via pi-pi stacking interactions and their activity and recoverability in the cycloaddition reaction were studied. The heterogenised catalyst onto reduced graphene oxide (4 a@rGO) was recycled several times although a loss of activity was observed. This catalyst was also used for the transformation of a series of epoxides under mild conditions.
    Thematic Areas: Química Physical and theoretical chemistry Organic chemistry Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências biológicas ii Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, physical Catalysis Biotecnología Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 1867-3880
    Author's mail: cyril.godard@urv.cat annamaria.masdeu@urv.cat
    Author identifier: 0000-0001-5762-4904 0000-0001-7938-3902
    Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cctc.202001816
    Funding program: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD
    Article's DOI: 10.1002/cctc.202001816
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2021
    Funding program action: VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS
  • Keywords:

    Catalysis,Chemistry, Physical,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
    Sustainable conversion
    Supported organocatalyst
    Reduced graphene oxides (rgo)
    Reduced graphene oxide
    Recoverability
    Organocatalysts
    Organic carbonates
    Nanotubes
    N-heterocyclic carbenes
    Metal-complexes
    Interactions
    Imidazolium salt
    Imidazolium carboxylates
    Heterogeneous catalysis
    Graphene oxide
    Graphene
    Dioxide
    Cycloaddition reaction
    Cycloaddition
    Cyclic carbonates
    Catalytic system
    Catalysts
    Carboxylation
    Carbon nanotubes
    Carbon materials
    Carbon material
    Carbon dioxide conversion
    Carbon dioxide
    Carbon beads
    Aromatic-compounds
    π ? interactions
    Química
    Physical and theoretical chemistry
    Organic chemistry
    Medicina i
    Materiais
    Interdisciplinar
    Inorganic chemistry
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Ciências biológicas ii
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Chemistry, physical
    Catalysis
    Biotecnología
    Astronomia / física
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