Articles producció científicaQuímica Física i Inorgànica

Th@D-5h(6)-C-80: a highly symmetric fullerene cage stabilized by a single metal ion

  • Identification data

    Identifier:  imarina:9218763
    Handle: https://hdl.handle.net/20.500.11797/imarina9218763
    Authors:  Yan, Yingjing; Morales-Martinez, Roser; Zhuang, Jiaxin; Yao, Yang-Rong; Li, Xiaomeng; Poblet, Josep M; Rodriguez-Fortea, Antonio; Chen, Ning
    Abstract:
    A novel endohedral metallofullerene (mono-EMF), Th@D-5h(6)-C-80, has been successfully synthesized and fully characterized by mass spectrometry, single crystal X-ray diffraction, UV-vis-NIR and Raman spectroscopy and cyclic voltammetry. Single crystal XRD analysis unambiguously assigned the fullerene cage as D-5h(6)-C-80, the first example in which the highly symmetric cage is stabilized by a single metal ion. The combined experimental and theoretical studies further reveal that the D-5h(6)-C-80 cage, known only for its stabilization by 6-electron transfer, is stabilized by the 4-electron transfer from the encapsulated Th ion for the first time.

  • Others:

    Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2021/cc/d1cc02339j
    APA: Yan, Yingjing; Morales-Martinez, Roser; Zhuang, Jiaxin; Yao, Yang-Rong; Li, Xiaomeng; Poblet, Josep M; Rodriguez-Fortea, Antonio; Chen, Ning (2021). Th@D-5h(6)-C-80: a highly symmetric fullerene cage stabilized by a single metal ion. Chemical Communications, 57(54), 6624-6627. DOI: 10.1039/d1cc02339j
    Paper original source: Chemical Communications. 57 (54): 6624-6627
    Article's DOI: 10.1039/d1cc02339j
    Journal publication year: 2021
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/acceptedVersion
    Record's date: 2024-10-12
    URV's Author/s: Morales Martínez, Roser / Poblet Rius, Josep Maria / Rodríguez Fortea, Antonio
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Yan, Yingjing; Morales-Martinez, Roser; Zhuang, Jiaxin; Yao, Yang-Rong; Li, Xiaomeng; Poblet, Josep M; Rodriguez-Fortea, Antonio; Chen, Ning
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Surfaces, coatings and films, Química, Metals and alloys, Medicina ii, Medicina i, Materials chemistry, Materiais, Interdisciplinar, General medicine, General chemistry, Farmacia, Engenharias iv, Engenharias iii, Engenharias ii, Engenharias i, Electronic, optical and magnetic materials, Ciências biológicas iii, Ciências biológicas ii, Ciências biológicas i, Ciências ambientais, Ciências agrárias i, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Chemistry, Ceramics and composites, Catalysis, Biotecnología, Biodiversidade, Astronomia / física
    Author's mail: josepmaria.poblet@urv.cat, antonio.rodriguezf@urv.cat

  • Keywords:

    Uv-vis nir
    Thorium metallography
    Theoretical study
    Single crystals
    Single crystal xrd
    Single crystal x-ray diffraction
    Sc3n-at-c-80
    Metals
    Metal ions
    Mass spectrometry
    Isomer
    Fullerenes
    Fullerene cages
    Endohedral metallofullerenes
    Cyclic voltammetry
    Cluster
    Cages (mine hoists)
    Catalysis
    Ceramics and Composites
    Chemistry
    Chemistry (Miscellaneous)
    Multidisciplinary
    Electronic
    Optical and Magnetic Materials
    Materials Chemistry
    Metals and Alloys
    Surfaces
    Coatings and Films
    Química
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Chemistry (all)
    Biotecnología
    Biodiversidade
    Astronomia / física

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