Articles producció científica> Enginyeria Química

Life Cycle Assessment of the Separation and Recycling of Fluorinated Gases Using Ionic Liquids in a Circular Economy Framework

  • Identification data

    Identifier: imarina:9241952
    Authors:
    Jovell, DanielPou, Josep O.Llovell, FelixGonzalez-Olmos, Rafael
    Abstract:
    The stricter regulation regarding the use of fluorinated gases (F-gases), as a consequence of their high Global Warming Potential (GWP), represents a challenge for the refrigeration industry. The design of alternatives requires the recycling of the low to moderate GWP compounds from current refrigerant blends. However, there is not a developed and standardized technology available to recover them, and once the life cycle of the refrigeration equipment has ended, most gases are incinerated. Fluorinated ionic liquids (FILs) can effectively perform as absorbents to the complex separation of F-gas mixtures. In this work, a methodology based on the COSMO-RS thermodynamic package integrated into an Aspen Plus process simulator was used to evaluate the performance of an FIL to recover difluoromethane (R-32) from the commercial blend R-407F. The environmental sustainability of the recovery process (circular economy scenario) was analyzed with a life cycle assessment (LCA) approach, comparing the obtained results with the conventional R-32 production (benchmark scenario). The results reveal a 30% recovery of 98 wt % R-32 suitable for further reuse with environmental load reduction in the 86-99% range compared to the R-32 production. This study can guide the development of new F-gas recovery technologies to improve the environmental impacts of these compounds from a circular economy perspective.
  • Others:

    Author, as appears in the article.: Jovell, Daniel; Pou, Josep O.; Llovell, Felix; Gonzalez-Olmos, Rafael;
    Department: Enginyeria Química
    URV's Author/s: Llovell Ferret, Fèlix Lluís
    Keywords: Solubility Refrigerants R134a Mixtures Life cycle assessment (lca) Ionic liquids Hydrofluoroethers Greenhouse gases Generation Fluorinated gases recovery Cosmo-rs Circular economy solubility refrigerants r134a mixtures life cycle assessment (lca) ionic liquids hydrofluoroethers generation cosmo-rs circular economy
    Abstract: The stricter regulation regarding the use of fluorinated gases (F-gases), as a consequence of their high Global Warming Potential (GWP), represents a challenge for the refrigeration industry. The design of alternatives requires the recycling of the low to moderate GWP compounds from current refrigerant blends. However, there is not a developed and standardized technology available to recover them, and once the life cycle of the refrigeration equipment has ended, most gases are incinerated. Fluorinated ionic liquids (FILs) can effectively perform as absorbents to the complex separation of F-gas mixtures. In this work, a methodology based on the COSMO-RS thermodynamic package integrated into an Aspen Plus process simulator was used to evaluate the performance of an FIL to recover difluoromethane (R-32) from the commercial blend R-407F. The environmental sustainability of the recovery process (circular economy scenario) was analyzed with a life cycle assessment (LCA) approach, comparing the obtained results with the conventional R-32 production (benchmark scenario). The results reveal a 30% recovery of 98 wt % R-32 suitable for further reuse with environmental load reduction in the 86-99% range compared to the R-32 production. This study can guide the development of new F-gas recovery technologies to improve the environmental impacts of these compounds from a circular economy perspective.
    Thematic Areas: Renewable energy, sustainability and the environment Química Materiais Interdisciplinar Green & sustainable science & technology General chemistry General chemical engineering Farmacia Environmental chemistry Engineering, chemical Engenharias ii Engenharias i Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemical engineering (miscellaneous) Chemical engineering (all) Biotecnología Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: felix.llovell@urv.cat
    Author identifier: 0000-0001-7109-6810
    Record's date: 2024-09-07
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://pubs.acs.org/doi/10.1021/acssuschemeng.1c04723
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Acs Sustainable Chemistry & Engineering. 10 (1): 71-80
    APA: Jovell, Daniel; Pou, Josep O.; Llovell, Felix; Gonzalez-Olmos, Rafael; (2022). Life Cycle Assessment of the Separation and Recycling of Fluorinated Gases Using Ionic Liquids in a Circular Economy Framework. Acs Sustainable Chemistry & Engineering, 10(1), 71-80. DOI: 10.1021/acssuschemeng.1c04723
    Article's DOI: 10.1021/acssuschemeng.1c04723
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2022
    Publication Type: Journal Publications
  • Keywords:

    Chemical Engineering (Miscellaneous),Chemistry (Miscellaneous),Chemistry, Multidisciplinary,Engineering, Chemical,Environmental Chemistry,Green & Sustainable Science & Technology,Renewable Energy, Sustainability and the Environment
    Solubility
    Refrigerants
    R134a
    Mixtures
    Life cycle assessment (lca)
    Ionic liquids
    Hydrofluoroethers
    Greenhouse gases
    Generation
    Fluorinated gases recovery
    Cosmo-rs
    Circular economy
    solubility
    refrigerants
    r134a
    mixtures
    life cycle assessment (lca)
    ionic liquids
    hydrofluoroethers
    generation
    cosmo-rs
    circular economy
    Renewable energy, sustainability and the environment
    Química
    Materiais
    Interdisciplinar
    Green & sustainable science & technology
    General chemistry
    General chemical engineering
    Farmacia
    Environmental chemistry
    Engineering, chemical
    Engenharias ii
    Engenharias i
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemical engineering (miscellaneous)
    Chemical engineering (all)
    Biotecnología
    Astronomia / física
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