Author, as appears in the article.: Pérez A; Lligadas G; Ronda JC; Galià M; Cádiz V
Department: Química Analítica i Química Orgànica
URV's Author/s: Cádiz Deleito, Maria Virginia / Galià Clua, Marina Teresa / Lligadas Puig, Gerard / PÉREZ DÍAZ, ANA MARÍA / Ronda Bargalló, Juan Carlos
Keywords: Transfer radical polymerization Thermogravimetric analysis Ring-opening polymerization Ring opening polymerization Renewable resources Renewable resource Polytrimethylene carbonate Poly (trimethylene carbonate) Metal-free atrp Metal-free atom transfer radical polymerization Metal free Free atoms Differential scanning calorimetry Diels-alder reaction Crosslinking Carbonation Block copolymers Block co polymers Atom-transfer radical polymerization Atom transfer radical polymerization thermal-degradation renewable resources raft polymerization networks metal-free atrp diels-alder reaction bearing aba triblock copolymer
Abstract: Block copolymers containing poly(trimethylene carbonate) (PTMC) middle block and poly(furfuryl methacrylate) PFMA end blocks were synthesized through sequential organocatalytic ring opening polymerization (ROP) of trimethylene carbonate and thermal and photoinitiated metal-free atom transfer radical polymerizations (ATRP) of furfuryl methacrylate. The thermal and mechanical properties of the triblock copolymers were studied by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and dynamical mechanical analysis (DMA). The crosslinking via Diels-Alder (DA) reaction between the furan groups of the block copolymers and bismaleimide and bisitaconimide was proved by FTIR and DSC and the thermoreversibility properties of the crosslinked polymer were subsequently investigated using DSC and solubility testing. © 2021 Elsevier Ltd
Thematic Areas: Química Polymers and plastics Polymer science Physics and astronomy (miscellaneous) Physics and astronomy (all) Organic chemistry Odontología Materials chemistry Materiais Interdisciplinar General physics and astronomy Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências ambientais Ciência de alimentos Ciência da computação Biotecnología Astronomia / física Arquitetura, urbanismo e design
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: marina.galia@urv.cat juancarlos.ronda@urv.cat gerard.lligadas@urv.cat
Author identifier: 0000-0002-4359-4510 0000-0002-0668-6600 0000-0002-8519-1840
Record's date: 2024-11-02
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://www.sciencedirect.com/science/article/pii/S0014305721006078?via%3Dihub
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: European Polymer Journal. 162
APA: Pérez A; Lligadas G; Ronda JC; Galià M; Cádiz V (2022). Thermoreversible poly(trimethylene carbonate)-based block copolymers containing reactive furfuryl groups via sequential ROP and ATRP. European Polymer Journal, 162(), -. DOI: 10.1016/j.eurpolymj.2021.110873
Article's DOI: 10.1016/j.eurpolymj.2021.110873
Entity: Universitat Rovira i Virgili
Journal publication year: 2022
Publication Type: Journal Publications
Repositori URV