Articles producció científica> Química Analítica i Química Orgànica

Thermoreversible poly(trimethylene carbonate)-based block copolymers containing reactive furfuryl groups via sequential ROP and ATRP

  • Identification data

    Identifier: imarina:9242245
    Handle: http://hdl.handle.net/20.500.11797/imarina9242245
  • Authors:

    Pérez A
    Lligadas G
    Ronda JC
    Galià M
    Cádiz V
  • Others:

    Author, as appears in the article.: Pérez A; Lligadas G; Ronda JC; Galià M; Cádiz V
    Department: Química Analítica i Química Orgànica
    URV's Author/s: Cádiz Deleito, Maria Virginia / Galià Clua, Marina Teresa / Lligadas Puig, Gerard / Ronda Bargalló, Juan Carlos
    Keywords: Transfer radical polymerization Thermogravimetric analysis Ring-opening polymerization Ring opening polymerization Renewable resources Renewable resource Polytrimethylene carbonate Poly (trimethylene carbonate) Metal-free atrp Metal-free atom transfer radical polymerization Metal free Free atoms Differential scanning calorimetry Diels-alder reaction Crosslinking Carbonation Block copolymers Block co polymers Atom-transfer radical polymerization Atom transfer radical polymerization thermal-degradation renewable resources raft polymerization networks metal-free atrp diels-alder reaction bearing aba triblock copolymer
    Abstract: Block copolymers containing poly(trimethylene carbonate) (PTMC) middle block and poly(furfuryl methacrylate) PFMA end blocks were synthesized through sequential organocatalytic ring opening polymerization (ROP) of trimethylene carbonate and thermal and photoinitiated metal-free atom transfer radical polymerizations (ATRP) of furfuryl methacrylate. The thermal and mechanical properties of the triblock copolymers were studied by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and dynamical mechanical analysis (DMA). The crosslinking via Diels-Alder (DA) reaction between the furan groups of the block copolymers and bismaleimide and bisitaconimide was proved by FTIR and DSC and the thermoreversibility properties of the crosslinked polymer were subsequently investigated using DSC and solubility testing. © 2021 Elsevier Ltd
    Thematic Areas: Química Polymers and plastics Polymer science Physics and astronomy (miscellaneous) Physics and astronomy (all) Organic chemistry Odontología Materials chemistry Materiais Interdisciplinar General physics and astronomy Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências ambientais Ciência de alimentos Ciência da computação Biotecnología Astronomia / física Arquitetura, urbanismo e design
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: gerard.lligadas@urv.cat virginia.cadiz@urv.cat juancarlos.ronda@urv.cat marina.galia@urv.cat
    Author identifier: 0000-0002-8519-1840 0000-0003-2689-5407 0000-0002-0668-6600 0000-0002-4359-4510
    Record's date: 2023-02-23
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://www.sciencedirect.com/science/article/pii/S0014305721006078?via%3Dihub
    Licence document URL: http://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: European Polymer Journal. 162
    APA: Pérez A; Lligadas G; Ronda JC; Galià M; Cádiz V (2022). Thermoreversible poly(trimethylene carbonate)-based block copolymers containing reactive furfuryl groups via sequential ROP and ATRP. European Polymer Journal, 162(), -. DOI: 10.1016/j.eurpolymj.2021.110873
    Article's DOI: 10.1016/j.eurpolymj.2021.110873
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2022
    Publication Type: Journal Publications
  • Keywords:

    Materials Chemistry,Organic Chemistry,Physics and Astronomy (Miscellaneous),Polymer Science,Polymers and Plastics
    Transfer radical polymerization
    Thermogravimetric analysis
    Ring-opening polymerization
    Ring opening polymerization
    Renewable resources
    Renewable resource
    Polytrimethylene carbonate
    Poly (trimethylene carbonate)
    Metal-free atrp
    Metal-free atom transfer radical polymerization
    Metal free
    Free atoms
    Differential scanning calorimetry
    Diels-alder reaction
    Crosslinking
    Carbonation
    Block copolymers
    Block co polymers
    Atom-transfer radical polymerization
    Atom transfer radical polymerization
    thermal-degradation
    renewable resources
    raft polymerization
    networks
    metal-free atrp
    diels-alder reaction
    bearing
    aba triblock copolymer
    Química
    Polymers and plastics
    Polymer science
    Physics and astronomy (miscellaneous)
    Physics and astronomy (all)
    Organic chemistry
    Odontología
    Materials chemistry
    Materiais
    Interdisciplinar
    General physics and astronomy
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Ciências ambientais
    Ciência de alimentos
    Ciência da computação
    Biotecnología
    Astronomia / física
    Arquitetura, urbanismo e design
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