Author, as appears in the article.: Li X; Villar-Yanez A; Ngassam Tounzoua C; Benet-Buchholz J; Grignard B; Bo C; Detrembleur C; Kleij AW
Department: Química Física i Inorgànica
URV's Author/s: Benet Buchholz, Jordi / Bo Jané, Carles / Villar Yanez, Alba
Keywords: Ring-opening polymerization Homogeneous catalysis Heterocycles Cascade reactions Carbon dioxide Alkyne-1,n-diols Alkyne-1, n-diols rearrangement propargylic alcohols homogeneous catalysis heterocycles epoxides diols conversion co2 chemicals catalytic strategies cascade reactions carbon dioxide atmospheric-pressure
Abstract: A silver-catalyzed cascade conversion of modular alkyne-1,n-diols and carbon dioxide has been developed allowing for the selective formation of keto-functionalized cyclic carbonates. The protocol is characterized by its operational simplicity, excellent scope of carbonate-based heterocycles, and mild reaction conditions. In situ IR studies, control experiments, and detailed computational analysis of these manifolds reveal the intermediacy of an α-alkylidene carbonate that is intercepted by an intramolecular alcohol nucleophile. The synthetic potential of this conceptually attractive CO2 transformation is demonstrated in the preparation of larger ring carbonates and their thermal rearrangement to sterically crowded, five-membered fused carbonate products.
Thematic Areas: Química Materiais Interdisciplinar General chemistry Engenharias ii Ciências agrárias i Chemistry, physical Chemistry (miscellaneous) Chemistry (all) Catalysis Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: carles.bo@urv.cat alba.villar@estudiants.urv.cat
Author identifier: 0000-0001-9581-2922
Record's date: 2024-09-07
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://pubs.acs.org/doi/10.1021/acscatal.1c05773
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Acs Catalysis. 12 (5): 2854-2860
APA: Li X; Villar-Yanez A; Ngassam Tounzoua C; Benet-Buchholz J; Grignard B; Bo C; Detrembleur C; Kleij AW (2022). Cascade Transformation of Carbon Dioxide and Alkyne-1, n-diols into Densely Substituted Cyclic Carbonates. Acs Catalysis, 12(5), 2854-2860. DOI: 10.1021/acscatal.1c05773
Article's DOI: 10.1021/acscatal.1c05773
Entity: Universitat Rovira i Virgili
Journal publication year: 2022
Publication Type: Journal Publications
Repositori URV