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Phthalate esters in marine ecosystems: Analytical methods, occurrence and distribution

  • Identification data

    Identifier: imarina:9249035
    Authors:
    Hidalgo-Serrano MBorrull FMarcé RMPocurull E
    Abstract:
    Phthalate esters are high production volume chemicals and are widely used as additives in the plastics industry. Since they are not chemically bound to the plastics, they can easily leach into the environment. They can also be transformed into phthalate monoesters via degradation or metabolization. As numerous studies have reported the negative effects of phthalate diesters and monoesters on marine biota, these contaminants are an emerging concern. In this article we review the most important analytical methods for determining phthalate esters in seawater, marine sediments and biota. The QuEChERS method and ultrasound-assisted extraction are the most common techniques for extracting solid samples, while solid-phase extraction is the most common technique for seawater samples. We also describe the occurrence and distribution of phthalate esters in the marine environment. Bis(2-ethylhexyl) phthalate, di-n-butyl phthalate and diisobutyl phthalate, as well as their metabolites, are the main compounds detected in the reviewed matrices.
  • Others:

    Author, as appears in the article.: Hidalgo-Serrano M; Borrull F; Marcé RM; Pocurull E
    Department: Química Analítica i Química Orgànica
    URV's Author/s: Borrull Ballarín, Francesc / Hidalgo Serrano, Míriam / Marcé Recasens, Rosa Maria / Pocurull Aixala, Eva
    Keywords: Seawater Phthalate esters Marine sediments Marine organisms Extraction techniques Analytical methods
    Abstract: Phthalate esters are high production volume chemicals and are widely used as additives in the plastics industry. Since they are not chemically bound to the plastics, they can easily leach into the environment. They can also be transformed into phthalate monoesters via degradation or metabolization. As numerous studies have reported the negative effects of phthalate diesters and monoesters on marine biota, these contaminants are an emerging concern. In this article we review the most important analytical methods for determining phthalate esters in seawater, marine sediments and biota. The QuEChERS method and ultrasound-assisted extraction are the most common techniques for extracting solid samples, while solid-phase extraction is the most common technique for seawater samples. We also describe the occurrence and distribution of phthalate esters in the marine environment. Bis(2-ethylhexyl) phthalate, di-n-butyl phthalate and diisobutyl phthalate, as well as their metabolites, are the main compounds detected in the reviewed matrices.
    Thematic Areas: Spectroscopy Química Medicina ii Interdisciplinar Farmacia Environmental chemistry Engenharias iv Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, analytical Biotecnología Astronomia / física Analytical chemistry
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: miriam.hidalgo@estudiants.urv.cat eva.pocurull@urv.cat rosamaria.marce@urv.cat francesc.borrull@urv.cat
    Author identifier: 0000-0001-6423-5851 0000-0001-5123-995X 0000-0002-5667-2899 0000-0003-2718-9336
    Record's date: 2024-09-07
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://www.sciencedirect.com/science/article/pii/S0165993622000814
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Trac-Trends In Analytical Chemistry. 151
    APA: Hidalgo-Serrano M; Borrull F; Marcé RM; Pocurull E (2022). Phthalate esters in marine ecosystems: Analytical methods, occurrence and distribution. Trac-Trends In Analytical Chemistry, 151(), -. DOI: 10.1016/j.trac.2022.116598
    Article's DOI: 10.1016/j.trac.2022.116598
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2022
    Publication Type: Journal Publications
  • Keywords:

    Analytical Chemistry,Chemistry, Analytical,Environmental Chemistry,Spectroscopy
    Seawater
    Phthalate esters
    Marine sediments
    Marine organisms
    Extraction techniques
    Analytical methods
    Spectroscopy
    Química
    Medicina ii
    Interdisciplinar
    Farmacia
    Environmental chemistry
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Chemistry, analytical
    Biotecnología
    Astronomia / física
    Analytical chemistry
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