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Complexed Biopolymer of Whey Protein and Carboxymethyl Cellulose to Enhance the Chemical Stability of Lemon Oil-in-Water Emulsions

  • Identification data

    Identifier: imarina:9258952
    Authors:
    Kaade WMéndez-Sánchez CGüell CDe Lamo-Castellví SMestres MFerrando M
    Abstract:
    Lemon oil (LO) has been used as a flavoring food additive and its encapsulation in emulsions has facilitated its incorporation in food and pharmaceutical products. d-Limonene, the main ingredient in LO, and citral, the compound responsible for the aromatic profile, are easily oxidized and a new emulsion interfacial structure is needed to protect these compounds. This paper studies the physical and chemical stabilities of LO-in-water emulsions produced by membrane emulsification as a function of the oil droplets’ surface electric charge and interfacial thickness. For that purpose, the different stabilizers used were whey protein (pH: 3.8 and 6.8), and, for the first time in lemon oil encapsulation, an electrostatic whey protein-carboxymethyl cellulose (WP-CMC) complex (pH: 3.8). Although this complex did not improve emulsions’ physical stability when it comes to droplet size, it has contributed to maintaining the emulsions’ original color. As for chemical stability, the WP-CMC complex decreased the production of off-flavors resulting from the deterioration of d-limonene and citral under accelerated oxidation conditions.
  • Others:

    Author, as appears in the article.: Kaade W; Méndez-Sánchez C; Güell C; De Lamo-Castellví S; Mestres M; Ferrando M
    Department: Enginyeria Química Química Analítica i Química Orgànica
    URV's Author/s: De Lamo Castellvi, Silvia / Ferrando Cogollos, Maria Montserrat / Güell Saperas, Maria Carmen / Méndez Sánchez, Carmen / Mestres Solé, Maria Montserrat
    Keywords: Whey protein Spg membrane emulsification Rich extract Physical/chemical stability Electrostatic complex whey protein physical/chemical stability parameters nanoemulsions flavor emulsification electrostatic complex components
    Abstract: Lemon oil (LO) has been used as a flavoring food additive and its encapsulation in emulsions has facilitated its incorporation in food and pharmaceutical products. d-Limonene, the main ingredient in LO, and citral, the compound responsible for the aromatic profile, are easily oxidized and a new emulsion interfacial structure is needed to protect these compounds. This paper studies the physical and chemical stabilities of LO-in-water emulsions produced by membrane emulsification as a function of the oil droplets’ surface electric charge and interfacial thickness. For that purpose, the different stabilizers used were whey protein (pH: 3.8 and 6.8), and, for the first time in lemon oil encapsulation, an electrostatic whey protein-carboxymethyl cellulose (WP-CMC) complex (pH: 3.8). Although this complex did not improve emulsions’ physical stability when it comes to droplet size, it has contributed to maintaining the emulsions’ original color. As for chemical stability, the WP-CMC complex decreased the production of off-flavors resulting from the deterioration of d-limonene and citral under accelerated oxidation conditions.
    Thematic Areas: Organic chemistry Food science & technology Food science Chemistry (miscellaneous) Analytical chemistry
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: carmen.mendez@urv.cat silvia.delamo@urv.cat silvia.delamo@urv.cat montserrat.mestres@urv.cat carme.guell@urv.cat carme.guell@urv.cat montse.ferrando@urv.cat montse.ferrando@urv.cat
    Author identifier: 0000-0002-5261-6806 0000-0002-5261-6806 0000-0001-9805-3482 0000-0002-4566-5132 0000-0002-4566-5132 0000-0002-2076-4222 0000-0002-2076-4222
    Record's date: 2024-09-07
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://pubs.acs.org/doi/10.1021/acsfoodscitech.1c00274
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Acs Food Science And Technology. 2 (1): 41-48
    APA: Kaade W; Méndez-Sánchez C; Güell C; De Lamo-Castellví S; Mestres M; Ferrando M (2022). Complexed Biopolymer of Whey Protein and Carboxymethyl Cellulose to Enhance the Chemical Stability of Lemon Oil-in-Water Emulsions. Acs Food Science And Technology, 2(1), 41-48. DOI: 10.1021/acsfoodscitech.1c00274
    Article's DOI: 10.1021/acsfoodscitech.1c00274
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2022
    Publication Type: Journal Publications
  • Keywords:

    Analytical Chemistry,Chemistry (Miscellaneous),Food Science,Food Science & Technology,Organic Chemistry
    Whey protein
    Spg membrane emulsification
    Rich extract
    Physical/chemical stability
    Electrostatic complex
    whey protein
    physical/chemical stability
    parameters
    nanoemulsions
    flavor
    emulsification
    electrostatic complex
    components
    Organic chemistry
    Food science & technology
    Food science
    Chemistry (miscellaneous)
    Analytical chemistry
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