Articles producció científica> Química Física i Inorgànica

Immobilized Molecular Catalysts for CO2 Photoreduction

  • Identification data

    Identifier: imarina:9261595
    Authors:
    Reguero, MarClaver, CarmenCarrilho, Rui Miguel BarrosoMasdeu-Bulto, Anna Maria
    Abstract:
    Catalytic carbon dioxide transformation to low valence carbon molecules such as carbon monoxide, formic acid, methanol and methane is a sustainable way to produce fuels and chemicals. Molecular catalysts can be designed to selectively transform CO2 at mild conditions, but a solvent medium is required. Instead, the molecular catalysts can be immobilized on solid supports to facilitate the continuous flow procedure and the separation of the products to recycle the catalytic systems for a more sustainable process. Photosensitive supports may also favor the light-absorbing steps and electron transfer processes. In this article, the recent results obtained in the photocatalytic CO2 reduction using catalytic systems formed by molecular compounds anchored on solids are reviewed.
  • Others:

    Author, as appears in the article.: Reguero, Mar; Claver, Carmen; Carrilho, Rui Miguel Barroso; Masdeu-Bulto, Anna Maria
    Department: Química Física i Inorgànica
    URV's Author/s: Claver Cabrero, Maria del Carmen Orosia / Masdeu Bultó, Anna Maria / Reguero de la Poza, Maria del Mar
    Keywords: Water oxidation Visible-light Supported catalysts Photochemical reduction Photocatalytic reduction Photocatalysis Para-terphenyl Molecular catalysts Metal-organic frameworks Immobilized catalysts Graphene oxide Formic-acid Cobalt complex Co2 reduction Co reduction 2 Carbon-dioxide reduction Anchored catalysts
    Abstract: Catalytic carbon dioxide transformation to low valence carbon molecules such as carbon monoxide, formic acid, methanol and methane is a sustainable way to produce fuels and chemicals. Molecular catalysts can be designed to selectively transform CO2 at mild conditions, but a solvent medium is required. Instead, the molecular catalysts can be immobilized on solid supports to facilitate the continuous flow procedure and the separation of the products to recycle the catalytic systems for a more sustainable process. Photosensitive supports may also favor the light-absorbing steps and electron transfer processes. In this article, the recent results obtained in the photocatalytic CO2 reduction using catalytic systems formed by molecular compounds anchored on solids are reviewed.
    Thematic Areas: Renewable energy, sustainability and the environment Materials science, multidisciplinary Green & sustainable science & technology General environmental science Environmental science (miscellaneous) Environmental science (all) Ciencias sociales
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: annamaria.masdeu@urv.cat carmen.claver@urv.cat mar.reguero@urv.cat
    Author identifier: 0000-0001-7938-3902 0000-0002-2518-7401 0000-0001-9668-8265
    Record's date: 2024-10-12
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://onlinelibrary.wiley.com/doi/10.1002/adsu.202100493
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Advanced Sustainable Systems. 6 (6): 2100493-
    APA: Reguero, Mar; Claver, Carmen; Carrilho, Rui Miguel Barroso; Masdeu-Bulto, Anna Maria (2022). Immobilized Molecular Catalysts for CO2 Photoreduction. Advanced Sustainable Systems, 6(6), 2100493-. DOI: 10.1002/adsu.202100493
    Article's DOI: 10.1002/adsu.202100493
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2022
    Publication Type: Journal Publications
  • Keywords:

    Environmental Science (Miscellaneous),Green & Sustainable Science & Technology,Materials Science, Multidisciplinary,Renewable Energy, Sustainability and the Environment
    Water oxidation
    Visible-light
    Supported catalysts
    Photochemical reduction
    Photocatalytic reduction
    Photocatalysis
    Para-terphenyl
    Molecular catalysts
    Metal-organic frameworks
    Immobilized catalysts
    Graphene oxide
    Formic-acid
    Cobalt complex
    Co2 reduction
    Co reduction 2
    Carbon-dioxide reduction
    Anchored catalysts
    Renewable energy, sustainability and the environment
    Materials science, multidisciplinary
    Green & sustainable science & technology
    General environmental science
    Environmental science (miscellaneous)
    Environmental science (all)
    Ciencias sociales
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