Author, as appears in the article.: Masdeu-Bulto, Anna M; Reguero, Mar; Claver, Carmen
Department: Química Física i Inorgànica
URV's Author/s: Claver Cabrero, Maria del Carmen Orosia / Masdeu Bultó, Anna Maria / Reguero de la Poza, Maria del Mar
Keywords: Selective photochemical reduction Reaction mechanisms Photocatalysis Molecular catalysts Density functional calculations Carbon dioxide reduction visible-light reaction mechanisms photocatalysis nickel(ii) complexes molecular catalysts molecular catalyst metal-complexes light photoredox catalysis highly efficient electrochemical reduction density functional calculations conversion carbon-dioxide reduction
Abstract: To stop the global warming, a complementary alternative to the decrease of CO2 production is the reduction of its amount in the atmosphere by capture and transformation into consumer products. One of the most interesting primary products is CO, used to synthesise liquid fuels. Perhaps the most attractive way of reducing CO2 to CO is the photocatalytic route. To know the details of the mechanism of this reaction can help in the design of more efficient catalytic systems. In this review, we compile the studies, undertaken from both computational and experimental approaches, of the reaction mechanism of the photoreduction of CO2 to CO by molecular catalytic systems based on transition metal complexes. The combination of experimental and computational studies can be crucial to achieve the goal aimed.
Thematic Areas: Química Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Chemistry, inorganic & nuclear Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: annamaria.masdeu@urv.cat carmen.claver@urv.cat mar.reguero@urv.cat
Author identifier: 0000-0001-7938-3902 0000-0002-2518-7401 0000-0001-9668-8265
Record's date: 2024-10-12
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejic.202100975
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: European Journal Of Inorganic Chemistry. 2022 (14): e202100975-
APA: Masdeu-Bulto, Anna M; Reguero, Mar; Claver, Carmen (2022). Mechanistic Insights of Photocatalytic CO2 Reduction: Experimental versus Computational Studies. European Journal Of Inorganic Chemistry, 2022(14), e202100975-. DOI: 10.1002/ejic.202100975
Article's DOI: 10.1002/ejic.202100975
Entity: Universitat Rovira i Virgili
Journal publication year: 2022
Publication Type: Journal Publications
Repositori URV