Author, as appears in the article.: Pala, Marc; Woods, Sarah E.; Hatton, Fiona L.; Lligadas, Gerard;
Department: Química Analítica i Química Orgànica
URV's Author/s: Lligadas Puig, Gerard / PALÀ SÁNCHEZ, MARC
Keywords: Transfer radical polymerization Thermoplastic elastomers Sterically hindered monomers Renewable resources Raft polymerization Mesoporous silica nanoparticles Lignocellulose Fragmentation chain transfer Ethyl lactate Diels-alder reaction Controlled radical polymerization Block polymers Bio-based chemicals Aba triblock copolymer
Abstract: Currently, most commodity chemicals and polymers are manufactured from nonrenewable petroleum-based resources. However, due to its finite nature and social claims about environment preservation, alternative sources of value-added and building block chemicals are being intensively studied. Renewable lignocellulosic biomass has offered an attractive replacement for fossil-based chemicals. Lignin and C5/C6 sugars obtained from lignocellulosic biomass through chemical and enzymatic methods can be further transformed to targeted chemical platforms. In the present review, synthetic pathways for well-defined poly(meth)acrylates obtained from C5/C6 sugar-derived platforms in which the sugar structure is not retained are discussed. While bio-based polymers from these monomers are investigated using a wide range of polymerization techniques, this study focuses on precise synthesis of macromolecular structures taking advantage of reversible-deactivation radical polymerization methods and their applications.
Thematic Areas: Química Polymers and plastics Polymer science Physical and theoretical chemistry Organic chemistry Materials chemistry Materiais Engenharias ii Condensed matter physics
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: marc.pala@urv.cat marc.pala@urv.cat gerard.lligadas@urv.cat
Author identifier: 0000-0002-8519-1840
Record's date: 2024-09-07
Papper version: info:eu-repo/semantics/publishedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Macromolecular Chemistry And Physics. 223 (13):
APA: Pala, Marc; Woods, Sarah E.; Hatton, Fiona L.; Lligadas, Gerard; (2022). RDRP (Meth)acrylic Homo and Block Polymers from Lignocellulosic Sugar Derivatives. Macromolecular Chemistry And Physics, 223(13), -. DOI: 10.1002/macp.202200005
Entity: Universitat Rovira i Virgili
Journal publication year: 2022
Publication Type: Journal Publications
Repositori URV