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RDRP (Meth)acrylic Homo and Block Polymers from Lignocellulosic Sugar Derivatives

  • Identification data

    Identifier: imarina:9261782
    Authors:
    Pala, MarcWoods, Sarah E.Hatton, Fiona L.Lligadas, Gerard
    Abstract:
    Currently, most commodity chemicals and polymers are manufactured from nonrenewable petroleum-based resources. However, due to its finite nature and social claims about environment preservation, alternative sources of value-added and building block chemicals are being intensively studied. Renewable lignocellulosic biomass has offered an attractive replacement for fossil-based chemicals. Lignin and C5/C6 sugars obtained from lignocellulosic biomass through chemical and enzymatic methods can be further transformed to targeted chemical platforms. In the present review, synthetic pathways for well-defined poly(meth)acrylates obtained from C5/C6 sugar-derived platforms in which the sugar structure is not retained are discussed. While bio-based polymers from these monomers are investigated using a wide range of polymerization techniques, this study focuses on precise synthesis of macromolecular structures taking advantage of reversible-deactivation radical polymerization methods and their applications.
  • Others:

    Author, as appears in the article.: Pala, Marc; Woods, Sarah E.; Hatton, Fiona L.; Lligadas, Gerard;
    Department: Química Analítica i Química Orgànica
    URV's Author/s: Lligadas Puig, Gerard / PALÀ SÁNCHEZ, MARC
    Keywords: Transfer radical polymerization Thermoplastic elastomers Sterically hindered monomers Renewable resources Raft polymerization Mesoporous silica nanoparticles Lignocellulose Fragmentation chain transfer Ethyl lactate Diels-alder reaction Controlled radical polymerization Block polymers Bio-based chemicals Aba triblock copolymer
    Abstract: Currently, most commodity chemicals and polymers are manufactured from nonrenewable petroleum-based resources. However, due to its finite nature and social claims about environment preservation, alternative sources of value-added and building block chemicals are being intensively studied. Renewable lignocellulosic biomass has offered an attractive replacement for fossil-based chemicals. Lignin and C5/C6 sugars obtained from lignocellulosic biomass through chemical and enzymatic methods can be further transformed to targeted chemical platforms. In the present review, synthetic pathways for well-defined poly(meth)acrylates obtained from C5/C6 sugar-derived platforms in which the sugar structure is not retained are discussed. While bio-based polymers from these monomers are investigated using a wide range of polymerization techniques, this study focuses on precise synthesis of macromolecular structures taking advantage of reversible-deactivation radical polymerization methods and their applications.
    Thematic Areas: Química Polymers and plastics Polymer science Physical and theoretical chemistry Organic chemistry Materials chemistry Materiais Engenharias ii Condensed matter physics
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: marc.pala@urv.cat marc.pala@urv.cat gerard.lligadas@urv.cat
    Author identifier: 0000-0002-8519-1840
    Record's date: 2024-09-07
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://onlinelibrary.wiley.com/doi/10.1002/macp.202200005
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Macromolecular Chemistry And Physics. 223 (13):
    APA: Pala, Marc; Woods, Sarah E.; Hatton, Fiona L.; Lligadas, Gerard; (2022). RDRP (Meth)acrylic Homo and Block Polymers from Lignocellulosic Sugar Derivatives. Macromolecular Chemistry And Physics, 223(13), -. DOI: 10.1002/macp.202200005
    Article's DOI: 10.1002/macp.202200005
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2022
    Publication Type: Journal Publications
  • Keywords:

    Condensed Matter Physics,Materials Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Polymer Science,Polymers and Plastics
    Transfer radical polymerization
    Thermoplastic elastomers
    Sterically hindered monomers
    Renewable resources
    Raft polymerization
    Mesoporous silica nanoparticles
    Lignocellulose
    Fragmentation chain transfer
    Ethyl lactate
    Diels-alder reaction
    Controlled radical polymerization
    Block polymers
    Bio-based chemicals
    Aba triblock copolymer
    Química
    Polymers and plastics
    Polymer science
    Physical and theoretical chemistry
    Organic chemistry
    Materials chemistry
    Materiais
    Engenharias ii
    Condensed matter physics
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