Articles producció científicaQuímica Física i Inorgànica

Site-Selective (Z)-alpha-Borylalkenyl Copper Systems for Nucleophilic Stereodefined Allylic Coupling

  • Identification data

    Identifier:  imarina:9280153
    Handle: https://hdl.handle.net/20.500.11797/imarina9280153
    Authors:  Pujol, Mireia; Maza, Ricardo J; Salvado, Oriol; Carbo, Jorge J; Fernandez, Elena
    Abstract:
    1,1-Diborylalkenes can be transformed into ( Z )-skipped dienes through Cu(I)-phosphine catalyzed allylic coupling reactions. The energetically preferred formation of ( Z )-α-borylalkenyl copper (I) species and the subsequent nucleophilic attack, explains the stereoselective nucleophilic substitution with allyl bromides. The eventual treatment of ( Z )-skipped dienes with NaO t Bu promotes cyclization/aromatization patterns via enyne intermediates.© 2022 Wiley-VCH GmbH.

  • Others:

    Link to the original source: https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202208495
    APA: Pujol, Mireia; Maza, Ricardo J; Salvado, Oriol; Carbo, Jorge J; Fernandez, Elena (2022). Site-Selective (Z)-alpha-Borylalkenyl Copper Systems for Nucleophilic Stereodefined Allylic Coupling. Angewandte Chemie (International Ed. Print), 61(37), e202208495-. DOI: 10.1002/anie.202208495
    Paper original source: Angewandte Chemie (International Ed. Print). 61 (37): e202208495-
    Article's DOI: 10.1002/anie.202208495
    Journal publication year: 2022
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2025-02-18
    URV's Author/s: Carbó Martin, Jorge Juan / Fernández Gutiérrez, Maria Elena / Maza Quiroga, Ricardo José / Pujol Baiges, Maria Cinta / Salvadó Ruiz, Oriol
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Pujol, Mireia; Maza, Ricardo J; Salvado, Oriol; Carbo, Jorge J; Fernandez, Elena
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Química, Medicina ii, Medicina i, Materiais, Interdisciplinar, General medicine, General chemistry, Farmacia, Engenharias ii, Ciências biológicas iii, Ciências biológicas ii, Ciências biológicas i, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Chemistry, Catalysis, Astronomia / física
    Author's mail: oriol.salvado@alumni.urv.cat, ricardojose.maza@estudiants.urv.cat, ricardojose.maza@estudiants.urv.cat, j.carbo@urv.cat, mariacinta.pujol@urv.cat, mariaelena.fernandez@urv.cat

  • Keywords:

    Stereoselective-synthesis
    Stereoselective synthesis
    Skipped dienes
    Copper
    Allylic coupling * copper * 1
    1-diborylalkenes * skipped dienes * stereoselective synthesis
    Allylic coupling
    1-diborylalkenes
    stereocontrolled approach
    hydroboration
    efficient synthesis
    alkynes
    acids
    Catalysis
    Chemistry
    Chemistry (Miscellaneous)
    Multidisciplinary
    Química
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Chemistry (all)
    Astronomia / física

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