Author, as appears in the article.: Guerrero, Federico; De la Flor, Silvia; Ramis, Xavier; Santos, Jose-Ignacio; Serra, Angels
Department: Enginyeria Mecànica Química Analítica i Química Orgànica
URV's Author/s: De la Flor Lopez, Silvia / Guerrero Ruiz, Federico / Serra Albet, Maria Angels
Keywords: Vitrimers Thermosets Poss Polyurethane Poly(thiourethane) Oligomeric silsesquioxane poss Nanocomposites Kinetics Epoxy Dielectric-properties Click reaction Chemistry
Abstract: Organic-inorganic hybrid materials combine the advantages of both phases: hardness and strength of inorganic phase and elasticity and toughness of the organic matrix. In the present study, we have prepared nanocomposites with a poly(thiourethane) polymeric matrix and silsesquioxane-type structures, with thiols as reactive groups (POSS-A or POSS-B, synthesized in different pressure conditions), looking for a covalent interaction between both phases, and good dispersion. Due to the click behavior of the reaction between the isocyanate and the thiol groups, highly homogeneous materials are obtained. Both monomers, catalyst (dibutyltin dilaurate, DBTDL), and the POSS precursor (3-mercaptopropyl trimethoxysilane, MPTMS), are commercially available, which present the advantage of being industrially scalable. The incorporation of POSS leads to an increase in glassy and rubbery storage moduli and the temperature of the maximum of tan delta curve. The vitrimeric behavior of the poly(thiourethanes) improved with the POSS incorporation, getting lower relaxation times. With a higher proportion of closed cages, POSS-B leads to the most significant improvements. All the materials prepared showed high transparency and the fracture of POSS modified materials indicates an improved toughness.
Thematic Areas: Química Polymers and plastics Polymer science Physics and astronomy (miscellaneous) Physics and astronomy (all) Organic chemistry Odontología Materials chemistry Materiais Interdisciplinar General physics and astronomy Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências ambientais Ciência de alimentos Ciência da computação Biotecnología Astronomia / física Arquitetura, urbanismo e design
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: angels.serra@urv.cat federico.guerrero@estudiants.urv.cat federico.guerrero@estudiants.urv.cat silvia.delaflor@urv.cat
Author identifier: 0000-0003-1387-0358 0000-0001-7163-4068 0000-0001-7163-4068 0000-0002-6851-1371
Record's date: 2024-11-02
Papper version: info:eu-repo/semantics/publishedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: European Polymer Journal. 174 111337-
APA: Guerrero, Federico; De la Flor, Silvia; Ramis, Xavier; Santos, Jose-Ignacio; Serra, Angels (2022). Novel hybrid organic/inorganic poly(thiourethane) covalent adaptable networks. European Polymer Journal, 174(), 111337-. DOI: 10.1016/j.eurpolymj.2022.111337
Entity: Universitat Rovira i Virgili
Journal publication year: 2022
Publication Type: Journal Publications
Repositori URV