Articles producció científica> Química Física i Inorgànica

On the determination of diffusion coefficients in two-component alloys and doped semiconductors. Several implications concerning the International Space Station

  • Identification data

    Identifier: imarina:9282543
    Authors:
    Sánchez ORuiz XPujalte MMercader IBatiste OGavaldà J
    Abstract:
    Abstract The accurate determination of mass diffusion coefficients is a technologically relevant problem that has implications on the modelling and control of material processes such as crystal growth and casting. It is also important in the validation of different theories of atomic diffusion. The experimental determination of these coefficients, when there is a liquid phase, is difficult due to the unavoidable presence of buoyancy driven convection currents that enhance mass transport and disturb diffusion measurements. To minimize as much as possible these problems, long capillaries are used in order to confine the fluid and reduce the intensity of the convective motions. These measurements have also been done in reduced gravity environments, but the residual gravity may still be able to induce buoyancy driven convection motions. The aim of our work is to analyze the impact of low solutal Rayleigh number environments on the accuracy of the interdiffusion coefficient measurements using long capillaries. In the present study we deal with two liquid systems; photovoltaic silicon and Al-based liquid binary alloys at high temperature. We have numerically simulated two different experimental techniques used to determine the diffusion coefficients; the shear cell and the long capillary techniques. We also consider the effect of rotating the cylindrical cell along their axis as a mechanism to reduce axial convective transport even in Earth laboratories. Finally, we use typical accelerometric signals from the International Space Station (ISS) in the quasi-steady range of frequencies. The signals concentrate on typical station reboosts because the accelerometric level of the rest of potentially dangerous disturbances - dockings, undockings and Extra Vehicular Activities, EVAs
  • Others:

    Author, as appears in the article.: Sánchez O; Ruiz X; Pujalte M; Mercader I; Batiste O; Gavaldà J
    Department: Química Física i Inorgànica
    URV's Author/s: Gavaldà Martínez, Josefa / Ruiz Martí, José Javier
    Keywords: Space stations Shear cells Shear cell Numerical simulation Microgravity conditions Melted semiconductors Mass diffusion coefficients Manned space flight Long capillaries Liquids Liquid metals International space stations Inter-diffusion coefficients Heat convection Extra vehicular activities Diffusion in solids Diffusion coefficients Diffusion Computer simulation Capillarity Buoyancy-driven convection Buoyancy Binary alloys
    Abstract: Abstract The accurate determination of mass diffusion coefficients is a technologically relevant problem that has implications on the modelling and control of material processes such as crystal growth and casting. It is also important in the validation of different theories of atomic diffusion. The experimental determination of these coefficients, when there is a liquid phase, is difficult due to the unavoidable presence of buoyancy driven convection currents that enhance mass transport and disturb diffusion measurements. To minimize as much as possible these problems, long capillaries are used in order to confine the fluid and reduce the intensity of the convective motions. These measurements have also been done in reduced gravity environments, but the residual gravity may still be able to induce buoyancy driven convection motions. The aim of our work is to analyze the impact of low solutal Rayleigh number environments on the accuracy of the interdiffusion coefficient measurements using long capillaries. In the present study we deal with two liquid systems; photovoltaic silicon and Al-based liquid binary alloys at high temperature. We have numerically simulated two different experimental techniques used to determine the diffusion coefficients; the shear cell and the long capillary techniques. We also consider the effect of rotating the cylindrical cell along their axis as a mechanism to reduce axial convective transport even in Earth laboratories. Finally, we use typical accelerometric signals from the International Space Station (ISS) in the quasi-steady range of frequencies. The signals concentrate on typical station reboosts because the accelerometric level of the rest of potentially dangerous disturbances - dockings, undockings and Extra Vehicular Activities, EVAs - is considerably lower. © 2015 Elsevier Ltd. All rights reserved.
    Thematic Areas: Thermodynamics Mechanics Mechanical engineering Materiais Matemática / probabilidade e estatística Interdisciplinar Geociências Fluid flow and transfer processes Engineering, mechanical Engenharias iv Engenharias iii Engenharias ii Engenharias i Condensed matter physics Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Biotecnología Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: fina.gavalda@urv.cat josepxavier.ruiz@urv.cat
    Author identifier: 0000-0001-7881-4192 0000-0003-4020-4457
    Record's date: 2024-09-07
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: https://www.sciencedirect.com/science/article/abs/pii/S0017931015002240
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: International Journal Of Heat And Mass Transfer. 86 508-518
    APA: Sánchez O; Ruiz X; Pujalte M; Mercader I; Batiste O; Gavaldà J (2015). On the determination of diffusion coefficients in two-component alloys and doped semiconductors. Several implications concerning the International Space Station. International Journal Of Heat And Mass Transfer, 86(), 508-518. DOI: 10.1016/j.ijheatmasstransfer.2015.02.061
    Article's DOI: 10.1016/j.ijheatmasstransfer.2015.02.061
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2015
    Publication Type: Journal Publications
  • Keywords:

    Condensed Matter Physics,Engineering, Mechanical,Fluid Flow and Transfer Processes,Mechanical Engineering,Mechanics,Thermodynamics
    Space stations
    Shear cells
    Shear cell
    Numerical simulation
    Microgravity conditions
    Melted semiconductors
    Mass diffusion coefficients
    Manned space flight
    Long capillaries
    Liquids
    Liquid metals
    International space stations
    Inter-diffusion coefficients
    Heat convection
    Extra vehicular activities
    Diffusion in solids
    Diffusion coefficients
    Diffusion
    Computer simulation
    Capillarity
    Buoyancy-driven convection
    Buoyancy
    Binary alloys
    Thermodynamics
    Mechanics
    Mechanical engineering
    Materiais
    Matemática / probabilidade e estatística
    Interdisciplinar
    Geociências
    Fluid flow and transfer processes
    Engineering, mechanical
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Condensed matter physics
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Biotecnología
    Astronomia / física
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