Author, as appears in the article.: Zúñiga C; Larrechi MS; Lligadas G; Ronda JC; Galià M; Cádiz V
Department: Química Analítica i Química Orgànica
URV's Author/s: Cádiz Deleito, Maria Virginia / Galià Clua, Marina Teresa / Larrechi García, Maria Soledad / Lligadas Puig, Gerard / Ronda Bargalló, Juan Carlos
Keywords: Statistical methods Statistical analysis Self-foaming Predictive models Polymer blends Polybenzoxazines Polybenzoxazine Mechanical properties Limiting oxygen index Foaming temperature Flame retardancy Compressive strength Compressive properties Compressive moduli
Abstract: Flame-retardant polybenzoxazine foams containing 1% phosphorus were prepared from diphenolic acid-based benzoxazine and 9,10-dihydro-9-oxa-10-(1-hydroxy-1-methylethyl)phosphaphenanthrene-10-oxide. Statistical predictive models were developed to determine the influence of the foaming time (tf) and foaming temperature (Tf) on the density, compressive modulus, and compressive strength of the foams. Results showed that the density of the foams exhibited great dependence on tf, whereas both compressive properties were more dependent on Tf and tf. Additionally, the flammability of the foams was also characterized by the limiting oxygen index. The presence of 9,10-dihydro-9-oxa-10-(1-hydroxy-1-methylethyl)phosphaphenanthrene-10-oxide greatly improved the flame retardancy of the resulting foams. © The Author(s) 2015.
Thematic Areas: Polymers and plastics Polymer science Materials chemistry General chemistry Engenharias ii Chemistry, applied Chemistry (miscellaneous) Chemistry (all)
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: marina.galia@urv.cat juancarlos.ronda@urv.cat gerard.lligadas@urv.cat
Author identifier: 0000-0002-4359-4510 0000-0002-0668-6600 0000-0002-8519-1840
Record's date: 2024-09-07
Papper version: info:eu-repo/semantics/acceptedVersion
Link to the original source: https://journals.sagepub.com/doi/abs/10.1177/0021955X16633647
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Journal Of Cellular Plastics. 52 (6): 657-669
APA: Zúñiga C; Larrechi MS; Lligadas G; Ronda JC; Galià M; Cádiz V (2016). Polybenzoxazine foams: Modeling mechanical properties. Journal Of Cellular Plastics, 52(6), 657-669. DOI: 10.1177/0021955X16633647
Article's DOI: 10.1177/0021955X16633647
Entity: Universitat Rovira i Virgili
Journal publication year: 2016
Publication Type: Journal Publications