Author, as appears in the article.: González S; Fernández E
Department: Química Física i Inorgànica
URV's Author/s: Fernández Gutiérrez, Maria Elena
Keywords: Α-boryl carbanions Light-induced reaction Boron-wittig Boron-ate suppression Borata-alkene Alkenylboronates water dicarbofunctionalization bromine boryl carbanions boron-wittig reaction boron ate suppression alkylideneboranes
Abstract: Carbolithiation of 1-phenylvinylboronic acid pinacol ester with tert-butyl lithium was used to generate α-phenylboryl carbanions which were reacted in a straightforward manner with carbonyl groups via boron-Wittig sequence. When unhindered α, β-unsaturated carbonyl compounds were used, 1, 4-addition of the α-phenylboryl carbanions was observed over the boron-Wittig sequence.
Thematic Areas: Química Organic chemistry Medicina ii Medicina i Materiais Interdisciplinar Farmacia Engenharias ii Ciências biológicas ii Ciências biológicas i Ciência de alimentos Chemistry, organic Biotecnología
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: mariaelena.fernandez@urv.cat
Author identifier: 0000-0001-9025-1791
Record's date: 2024-08-03
Papper version: info:eu-repo/semantics/acceptedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Synlett. 34 (12): 1409-1414
APA: González S; Fernández E (2023). Alkenylboronic ester activation to nucleophilic addition and electrophilic trapping with carbonyl groups. Synlett, 34(12), 1409-1414. DOI: 10.1055/a-1954-3236
Entity: Universitat Rovira i Virgili
Journal publication year: 2023
Publication Type: Journal Publications
Repositori URV