Author, as appears in the article.: Comí M; Lligadas G; Ronda JC; Galià M; Cádiz V
Department: Química Analítica i Química Orgànica
URV's Author/s: Cádiz Deleito, Maria Virginia / Galià Clua, Marina Teresa / Lligadas Puig, Gerard / Ronda Bargalló, Juan Carlos
Keywords: Thiol-enes Thiol-ene/yne coupling Thermal and mechanical properties Propargyl Post-modification Polyurethanes Nuclear magnetic resonance spectroscopy Mechanical properties Isophorone diisocyanate Hydrocarbons Glass transition Functionalizations Functionalization Fourier transform infrared spectroscopy Castor oil-based polyurethanes Bio-based polymers Allyl- and propargyl-containing diols
Abstract: An efficient route to obtain allyl- and propargyl-containing diols from 10-undecen-1-ol, and their polymerization with isophorone diisocyanate to produce alkene- and alkyne-functionalized polyurethanes (PUs) is described. The bio-based PUs have been further modified by thiol-ene/yne coupling of thioglycerol into unsaturation to obtain a series of PUs with enhanced hydrophilicity. All the synthesized PUs were characterized by FTIR-ATR and NMR spectroscopy. As expected, the PUs were amorphous and DSC revealed glass transition temperatures in the range of 40 °C–5 °C for the PUs before and after modification. The PUs exhibited highly tunable thermal and mechanical properties. The mechanical properties of these bio-based polymers (E modulus from 774 MPa to 6 MPa and at break from 45% to 401%) make the suitable materials for a large range of applications. © 2016 Elsevier Ltd
Thematic Areas: Química Polymers and plastics Polymer science Organic chemistry Medicina ii Materials chemistry Materiais Interdisciplinar Farmacia Engenharias iv Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Biotecnología Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: marina.galia@urv.cat juancarlos.ronda@urv.cat gerard.lligadas@urv.cat
Author identifier: 0000-0002-4359-4510 0000-0002-0668-6600 0000-0002-8519-1840
Record's date: 2024-09-07
Papper version: info:eu-repo/semantics/acceptedVersion
Link to the original source: https://www.sciencedirect.com/science/article/abs/pii/S0032386116308576
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Polymer. 103 163-170
APA: Comí M; Lligadas G; Ronda JC; Galià M; Cádiz V (2016). Synthesis of castor-oil based polyurethanes bearing alkene/alkyne groups and subsequent thiol-ene/yne post-modification. Polymer, 103(), 163-170. DOI: 10.1016/j.polymer.2016.09.057
Article's DOI: 10.1016/j.polymer.2016.09.057
Entity: Universitat Rovira i Virgili
Journal publication year: 2016
Publication Type: Journal Publications
Repositori URV