Articles producció científica> Enginyeria Electrònica, Elèctrica i Automàtica

Hydrophobic-oleophilic surfaces based on chemical modification of nanoporous alumina

  • Identification data

    Identifier: imarina:9295597
    Authors:
    Formentin, PilarAcosta, Laura KMarsal, Lluis F
    Abstract:
    Hydrophobic/oleophilic nanoporous anodic alumina substrates were fabricated by two-step anodization method following of chemical modification with 1H, 1H, 2H, 2H-perfluorooctyltrichlorosilane (FOTS). Surface morphology was characterized using a scanning electron microscopy. The influence of the topography and the pore size of the surface in the contact angle measurements with different solvents have been studied. The water repellence capacity of the nanoporous anodic alumina structure as fabricated depends on pore diameter but, there is a critical value of pore size beyond which the water contact angle decrease. After chemical modification of the surface, this effect is not observed. The porous topography of the material is not an advantage for the oleophibicity. The CA values for the non-porous surface using different solvents are lower than the structured surface. The results obtained in this study can be used to desire wettability properties. Modified NAA exhibit hydrophobicity and at the same time permeability for solvents with low surface tension.
  • Others:

    Author, as appears in the article.: Formentin, Pilar; Acosta, Laura K; Marsal, Lluis F
    Department: Enginyeria Electrònica, Elèctrica i Automàtica
    URV's Author/s: Acosta Capilla, Laura Karen / Formentín Vallés, Pilar / Marsal Garví, Luis Francisco
    Keywords: Wettability Surface modification Oleophilic surface Nanoporous anodic alumina Hydrophobicity Anodic alumina wettability surface modification solid-surfaces resistance oleophilic surface oil nanowires hydrophobicity fabrication arrays anodization adhesion
    Abstract: Hydrophobic/oleophilic nanoporous anodic alumina substrates were fabricated by two-step anodization method following of chemical modification with 1H, 1H, 2H, 2H-perfluorooctyltrichlorosilane (FOTS). Surface morphology was characterized using a scanning electron microscopy. The influence of the topography and the pore size of the surface in the contact angle measurements with different solvents have been studied. The water repellence capacity of the nanoporous anodic alumina structure as fabricated depends on pore diameter but, there is a critical value of pore size beyond which the water contact angle decrease. After chemical modification of the surface, this effect is not observed. The porous topography of the material is not an advantage for the oleophibicity. The CA values for the non-porous surface using different solvents are lower than the structured surface. The results obtained in this study can be used to desire wettability properties. Modified NAA exhibit hydrophobicity and at the same time permeability for solvents with low surface tension.
    Thematic Areas: Química Odontología Medicina ii Materials science, multidisciplinary Materials science (miscellaneous) Materials science (all) Materials science Materiais Interdisciplinar Geociências General materials science Farmacia Ensino Engenharias iv Engenharias iii Engenharias ii Engenharias i Condensed matter physics Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Biotecnología Biodiversidade Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: laurakaren.acosta@urv.cat lluis.marsal@urv.cat pilar.formentin@urv.cat pilar.formentin@urv.cat
    Author identifier: 0000-0002-5976-1408
    Record's date: 2024-10-12
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://www.sciencedirect.com/science/article/pii/S0254058423003942
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Materials Chemistry And Physics. 302 127686-
    APA: Formentin, Pilar; Acosta, Laura K; Marsal, Lluis F (2023). Hydrophobic-oleophilic surfaces based on chemical modification of nanoporous alumina. Materials Chemistry And Physics, 302(), 127686-. DOI: 10.1016/j.matchemphys.2023.127686
    Article's DOI: 10.1016/j.matchemphys.2023.127686
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2023
    Publication Type: Journal Publications
  • Keywords:

    Condensed Matter Physics,Materials Science,Materials Science (Miscellaneous),Materials Science, Multidisciplinary
    Wettability
    Surface modification
    Oleophilic surface
    Nanoporous anodic alumina
    Hydrophobicity
    Anodic alumina
    wettability
    surface modification
    solid-surfaces
    resistance
    oleophilic surface
    oil
    nanowires
    hydrophobicity
    fabrication
    arrays
    anodization
    adhesion
    Química
    Odontología
    Medicina ii
    Materials science, multidisciplinary
    Materials science (miscellaneous)
    Materials science (all)
    Materials science
    Materiais
    Interdisciplinar
    Geociências
    General materials science
    Farmacia
    Ensino
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Condensed matter physics
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Biotecnología
    Biodiversidade
    Astronomia / física
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