Author, as appears in the article.: Guardià, J; Giamberini, M; Reina, JA; Montané, X
Department: Enginyeria Química Química Analítica i Química Orgànica
URV's Author/s: Giamberini, Marta / Guardià Blanch, Jordi / Montané Montané, Xavier / Reina Lozano, José Antonio
Keywords: Supramolecular structures Side chain liquid crystalline polymers Ring-opening polymerization Poly(2-oxazoline)s Columnar mesophase Cationic ring-opening polymerization Biomimetic transport temperature supramolecular structures side chain liquid crystalline polymers polyoxazolines models macromolecules family design derivatives conducting membranes columnar mesophase cationic ring-opening polymerization biomimetic
Abstract: The polymerization of dendronized monomers is an attractive option to synthesize liquid crystalline columnar polymers with side chain dendrons. Following this approach, we report for the first time in the present study the synthesis of a family of side chain liquid crystalline (SCLC) poly(2-oxazoline)s, poly(2-(3,4,5-tris(4-dodecyloxybenzyloxy)phenyl)-2-oxazoline) (PTOx) from its oxazoline monomer precursor, 2-(3,4,5-tris(4-dodecyloxybenzyloxy)phenyl)-4,5-dihydro-1,3-oxazole) (TAPOx), by cationic ring-opening polymerization (CROP). The optimisation of the reaction parameters (temperature, type of initiator, terminating agent, solvent and monomer concentration), combined with the nature of the CROP allowed us to obtain high molecular weight SCLC poly(2-oxazoline)s. NMR investigations were consistent with the targeted molecular weights of the synthesized PTOx and the living nature of TAPOx polymerization. Regarding the mesomorphic characterization, all synthesized acyl-substituted poly(ethyleneimine)s exhibited liquid crystalline mesophases in a broad temperature range. XRD studies demonstrated that these dendronized poly(2-oxazoline)s self-assemble into columnar structures. Mesomorphic and thermal properties suggest that these family of poly(2-oxazoline)s could be excellent candidates to build up membranes for proton transport applications.
Thematic Areas: Química Polymers and plastics Polymer science Physics and astronomy (miscellaneous) Physics and astronomy (all) Organic chemistry Odontología Materials chemistry Materiais Interdisciplinar General physics and astronomy Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências ambientais Ciência de alimentos Ciência da computação Biotecnología Astronomia / física Arquitetura, urbanismo e design
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: xavier.montane@urv.cat jordi.guardia@alumni.urv.cat marta.giamberini@urv.cat joseantonio.reina@urv.cat
Author identifier: 0000-0002-1426-239X 0000-0003-1345-3140 0000-0001-8278-3552 0000-0002-9245-4135
Record's date: 2024-11-02
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://www.sciencedirect.com/science/article/pii/S0014305723004561
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: European Polymer Journal. 196
APA: Guardià, J; Giamberini, M; Reina, JA; Montané, X (2023). Synthesis and characterization of dendronized side chain liquid crystalline Poly(2-oxazoline)s towards biomimetic ion channels. European Polymer Journal, 196(), -. DOI: 10.1016/j.eurpolymj.2023.112273
Article's DOI: 10.1016/j.eurpolymj.2023.112273
Entity: Universitat Rovira i Virgili
Journal publication year: 2023
Publication Type: Journal Publications
Repositori URV