Author, as appears in the article.: Zhang, JY; Bhattacharya, S; Khsara, BE; Nisar, T; Muller, A; Besora, M; Poblet, JM; Wagner, V; Kuhnert, N; Kortz, U
Department: Química Física i Inorgànica
URV's Author/s: Besora Bonet, Maria / Poblet Rius, Josep Maria
Keywords: Molecular-orbital methods platinum(iv) o-xylene hydrogenation nmr chemical-shifts mesoporous silica gas-phase exchange crystal catalyst basis-sets
Abstract: The first PtIV-containing discrete polyoxoplatinate(II) [PtIVPtII6O6(AsO2(CH3)2)6]2- (Pt7) and polyoxopalladate(II) [PtIVPdII6O6(AsO2(CH3)2)6]2- (PtPd6) have been prepared and characterized in the solid state, in solution, and in the gas phase. The molecular structures of the noble metal-oxo clusters Pt7 and PtPd6 comprise a central, octahedral PtIVO6 hetero group surrounded by six square-planar MO4 (M = PtII, PdII) units, which are capped by six dimethylarsinate ligands. The polyanions were prepared under simple one-pot aqueous solution conditions by reacting H2Pt(OH)6 with either K2PtCl4 or Pd(NO3)2 in sodium dimethylarsinate buffer (pH 7) at 80 °C. Catalytic studies were performed on Pt7 supported on SBA15-apts for o-xylene hydrogenation at 300 °C and 90 bar H2 pressure and indicated excellent activity and recyclability with low activation temperature.
Thematic Areas: Química Physical and theoretical chemistry Medicina i Materiais Interdisciplinar Inorganic chemistry General medicine Farmacia Engenharias iii Engenharias ii Engenharias i Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Chemistry, inorganic & nuclear Chemistry (miscellaneous) Biotecnología Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: maria.besora@urv.cat josepmaria.poblet@urv.cat
Author identifier: 0000-0002-6656-5827 0000-0002-4533-0623
Record's date: 2024-08-03
Papper version: info:eu-repo/semantics/acceptedVersion
Link to the original source: https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c00832
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Inorganic Chemistry. 62 (33): 13184-13194
APA: Zhang, JY; Bhattacharya, S; Khsara, BE; Nisar, T; Muller, A; Besora, M; Poblet, JM; Wagner, V; Kuhnert, N; Kortz, U (2023). Pt-IV-Containing Hexaplatinate(II) [(PtPtII)-Pt-IV O-6(6)(AsO2(CH3)(2))(6)](2-) and Hexapalladate(II) [(PtPdII)-Pd-IV O-6(6)(AsO2(CH3)(2))(6)](2-). Inorganic Chemistry, 62(33), 13184-13194. DOI: 10.1021/acs.inorgchem.3c00832
Article's DOI: 10.1021/acs.inorgchem.3c00832
Entity: Universitat Rovira i Virgili
Journal publication year: 2023
Publication Type: Journal Publications
Repositori URV