Articles producció científica> Química Física i Inorgànica

Metal-Organic Frameworks Photocatalyst Through Plasmon-Induced Hot-Electrons

  • Identification data

    Identifier: imarina:9378587
    Handle: https://hdl.handle.net/20.500.11797/imarina9378587
    Authors:
    Zorlu, TolgaBecerril-Castro, I BrianSousa-Castillo, AnaPuertolas, BegonaBesteiro, Lucas VWang, ZhimingGovorov, AlexanderCorrea-Duarte, Miguel AAlvarez-Puebla, Ramon A
    Abstract:
    Plasmonic metal-organic frameworks (plasmonic-MOFs) ingeniously meld the homogeneous and vast porosity of MOFs with the distinctive plasmonic characteristics of metallic nanoparticles (NPs), creating a powerful synergy. This innovative combination is leveraged for enhanced plasmon-induced hot-electron photocatalysis, particularly within polystyrene beads adorned with silver nanoparticles (AgNPs) and encapsulated by zeolitic imidazolate framework-8 (ZIF-8). The strategic incorporation of AgNPs into this composite material generates hot carriers, significantly enhancing the catalytic performance of ZIF-8. This approach not only exemplifies the potential for advanced photocatalytic processes of MOFs, but also paves the way for groundbreaking applications in environmental remediation and sustainable chemistry. Plasmonic metal-organic frameworks combine the extensive porosity of MOFs with the unique plasmonic properties of metallic nanoparticles, enhancing plasmon-induced hot-electron photocatalysis. image

  • Others:

    Author, as appears in the article.: Zorlu, Tolga; Becerril-Castro, I Brian; Sousa-Castillo, Ana; Puertolas, Begona; Besteiro, Lucas V; Wang, Zhiming; Govorov, Alexander; Correa-Duarte, Miguel A; Alvarez-Puebla, Ramon A
    Department: Química Física i Inorgànica
    URV's Author/s: Alvarez Puebla, Ramon Angel / Zorlu, Tolga
    Keywords: Agnps Behavio Hot-carrier injection Hot-electrons Mofs Nanoparticles Photocatalysis Zeolitic imidazolate framework-8 Zif- Zif-8
    Abstract: Plasmonic metal-organic frameworks (plasmonic-MOFs) ingeniously meld the homogeneous and vast porosity of MOFs with the distinctive plasmonic characteristics of metallic nanoparticles (NPs), creating a powerful synergy. This innovative combination is leveraged for enhanced plasmon-induced hot-electron photocatalysis, particularly within polystyrene beads adorned with silver nanoparticles (AgNPs) and encapsulated by zeolitic imidazolate framework-8 (ZIF-8). The strategic incorporation of AgNPs into this composite material generates hot carriers, significantly enhancing the catalytic performance of ZIF-8. This approach not only exemplifies the potential for advanced photocatalytic processes of MOFs, but also paves the way for groundbreaking applications in environmental remediation and sustainable chemistry. Plasmonic metal-organic frameworks combine the extensive porosity of MOFs with the unique plasmonic properties of metallic nanoparticles, enhancing plasmon-induced hot-electron photocatalysis. image
    Thematic Areas: Astronomia / física Biomaterials Chemistry (all) Chemistry (miscellaneous) Chemistry, multidisciplinary Chemistry, physical Ciências agrárias i Condensed matter physics Electrochemistry Electronic, optical and magnetic materials Engenharias ii Engenharias iv General chemistry General materials science Materiais Materials science (all) Materials science (miscellaneous) Materials science, multidisciplinary Nanoscience & nanotechnology Nanoscience and nanotechnology Physics, applied Physics, condensed matter Química
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: tolga.zorlu@estudiants.urv.cat ramon.alvarez@urv.cat
    Author identifier: 0000-0001-7650-2152 0000-0003-4770-5756
    Record's date: 2025-02-18
    Paper version: info:eu-repo/semantics/publishedVersion
    Paper original source: Advanced Functional Materials. 34 (51):
    APA: Zorlu, Tolga; Becerril-Castro, I Brian; Sousa-Castillo, Ana; Puertolas, Begona; Besteiro, Lucas V; Wang, Zhiming; Govorov, Alexander; Correa-Duarte, M (2024). Metal-Organic Frameworks Photocatalyst Through Plasmon-Induced Hot-Electrons. Advanced Functional Materials, 34(51), -. DOI: 10.1002/adfm.202410352
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2024
    Publication Type: Journal Publications

  • Keywords:

    Biomaterials,Chemistry (Miscellaneous),Chemistry, Multidisciplinary,Chemistry, Physical,Condensed Matter Physics,Electrochemistry,Electronic, Optical and Magnetic Materials,Materials Science (Miscellaneous),Materials Science, Multidisciplinary,Nanoscience & Nanotechnology,Nanoscience and Nanotechnology,Physics, Applied,Physics, Condensed M
    Agnps
    Behavio
    Hot-carrier injection
    Hot-electrons
    Mofs
    Nanoparticles
    Photocatalysis
    Zeolitic imidazolate framework-8
    Zif-
    Zif-8
    Astronomia / física
    Biomaterials
    Chemistry (all)
    Chemistry (miscellaneous)
    Chemistry, multidisciplinary
    Chemistry, physical
    Ciências agrárias i
    Condensed matter physics
    Electrochemistry
    Electronic, optical and magnetic materials
    Engenharias ii
    Engenharias iv
    General chemistry
    General materials science
    Materiais
    Materials science (all)
    Materials science (miscellaneous)
    Materials science, multidisciplinary
    Nanoscience & nanotechnology
    Nanoscience and nanotechnology
    Physics, applied
    Physics, condensed matter
    Química

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