Author, as appears in the article.: Díaz-Cortés, A; Del Valle, H; López-Polín, L; Cáceres, I; Valtierra, N; Pineda, A; Saladié, P; Vallverdú, J; Otero, J
Department: Història i Història de l'Art
URV's Author/s: Cáceres Cuello de Oro, Isabel / López-Polin Dolhaberriague, Lucía / Saladié Ballesté, Palmira
Keywords: Archaeological bones Atr Barranc Bioapatit Bioapatite Collagen Conservation diagnosis Consolidant Cultural heritage Delta-o-18 values Diagenesis Fossil Ftir Hydroxyapatite Infrared-spectroscopy Organic-solvent removal Site
Abstract: Initial physicochemical assessment of cultural materials plays a critical role in the research and management of cultural heritage, serving as a foundation for comprehending deterioration mechanisms and developing effective conservation treatments. However, this knowledge is more advanced in several cultural materials such as artwork or historic buildings, than in bone and fossils. This study focuses on bone material conservation, applying diagenetic methods for characterizing and assessing the state of conservation of archaeological bones from Pit 1 at Barranc de la Boella (BB), an open-air archaeological site from the late Early Pleistocene, from a conservation perspective. Microstructural analyses, including mercury intrusion porosimetry (MIP) and histological analysis, alongside microchemical analyses through Attenuated Total Reflection Fourier Transform Infrared (ATR-FTIR), and FTIR with KBr pellets and X-ray Diffraction (XRD), were conducted to evaluate the decay processes affecting the bones. Results indicated poor bone preservation characterized by high porosity, significant microbial attack, collagen degradation, and the potential recrystallization of bioapatite into fluorapatite. These findings underscore the substantial challenges presented by open-site conditions to preservation efforts and highlight the need for suitable conservation treatments, such as consolidation to reinforce the microstructure. The study emphasizes the importance of characterizing archaeological bones to understand the factors influencing their preservation states and guide conservation works in this material. This work contributes to the knowledge of diagenesis studies to standardize the diagnosis of the state of conservation on archaeological bones.
Thematic Areas: Administração pública e de empresas, ciências contábeis e turismo Analytical chemistry Astronomia / física Biodiversidade Biotecnología Chemistry, analytical Ciência de alimentos Ciências agrárias i Ciências ambientais Ciências biológicas i Ciências biológicas ii Ciências biológicas iii Enfermagem Engenharias i Engenharias ii Engenharias iii Engenharias iv Farmacia Geociências Interdisciplinar Materiais Medicina i Medicina ii Nutrição Odontología Química Saúde coletiva Spectroscopy
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: isabel.caceres@urv.cat palmira.saladie@urv.cat lucia.lopezpolin@urv.cat
Author identifier: 0000-0001-8487-2591 0000-0002-1730-8461 0000-0002-5810-4115
Record's date: 2024-09-14
Papper version: info:eu-repo/semantics/publishedVersion
Papper original source: Microchemical Journal. 206 111353-
APA: Díaz-Cortés, A; Del Valle, H; López-Polín, L; Cáceres, I; Valtierra, N; Pineda, A; Saladié, P; Vallverdú, J; Otero, J (2024). Diagnosis of archaeological bones: Analyzing the state of conservation of lower Pleistocene bones through diagenesis methods. Microchemical Journal, 206(), 111353-. DOI: 10.1016/j.microc.2024.111353
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Entity: Universitat Rovira i Virgili
Journal publication year: 2024
Publication Type: Journal Publications