Author, as appears in the article.: Palà M; Lligadas G; Moreno A
Department: Química Analítica i Química Orgànica
URV's Author/s: Lligadas Puig, Gerard / Moreno Guerra, Adrian / Moreno Ribas, Antonio / PALÀ SÁNCHEZ, MARC
Keywords: Ethyl lactate Green solvent Lactic-acid Ligni Lignocellulosic biomass Living radical polymerization Mechanical-properties Platform Raft polymerization Tunable lcst
Abstract: (Meth)acrylic polymers are massively produced due to their inherently attractive properties. However, the vast majority of these polymers are derived from fossil resources, which is not aligned with the tendency to reduce gas emissions. In this context, (meth)acrylic polymers derived from biomass (biobased polymers) are gaining momentum, as their application in different areas can not only stand the comparison but even surpass, in some cases, the performance of petroleum-derived ones. In this review, we highlight the design and synthesis of (meth)acrylic polymers derived from lactate esters (LEs) and lactate amides (LAs), both derived from lactic acid. While biobased polymers have been widely studied and reviewed, the poly(meth)acrylates with pendant LE and LA moieties evolved slowly until recently when significant achievements have been made. Hence, constraints and opportunities arising from previous research in this area are presented, focusing on the synthesis of well-defined polymers for the preparation of advanced materials.
Thematic Areas: Astronomia / física Biochemistry & molecular biology Bioengineering Biomaterials Biotecnología Chemistry, organic Ciência de alimentos Ciências agrárias i Ciências biológicas i Ciências biológicas ii Ciências biológicas iii Engenharias ii Engenharias iv Farmacia Interdisciplinar Materiais Materials chemistry Medicina ii Polymer science Polymers and plastics Química
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: gerard.lligadas@urv.cat antonio.moreno@urv.cat marc.pala@urv.cat adrian.moreno@urv.cat marc.pala@urv.cat
Author identifier: 0000-0002-8519-1840 0000-0003-3945-2314
Record's date: 2024-10-26
Papper version: info:eu-repo/semantics/publishedVersion
Papper original source: Biomacromolecules. 25 (10): 6338-6356
APA: Palà M; Lligadas G; Moreno A (2024). Valorization of Lactate Esters and Amides into Value-Added Biobased (Meth)acrylic Polymers. Biomacromolecules, 25(10), 6338-6356. DOI: 10.1021/acs.biomac.4c00891
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Entity: Universitat Rovira i Virgili
Journal publication year: 2024
Publication Type: Journal Publications
Repositori URV