Articles producció científicaQuímica Física i Inorgànica

α-Boryl Carbanions: The Influence of Geminal Heteroatoms in C-C Bond Formation

  • Identification data

    Identifier:  imarina:9440133
    Handle: https://hdl.handle.net/20.500.11797/imarina9440133
    Authors:  Fernández, E
    Abstract:
    The wide applications of alpha-boryl carbanions in selective coupling with organohalides, imines/carbonyls and conjugated unsaturated substrates has become an interesting tool for organic synthesis. Strategically, the inclusion of heteroatoms, such as Si, S, N, F, Cl, Br and I in the alpha position opens a new venue towards multifunctionalities in molecular design. Here, a conceptual and practical view on powerful carbanions, containing alpha-silicoboron, alpha-thioboron, alpha-haloboron and alpha-aminoboron is given, as well as a prespective on their efficient application for selective electrophilic trapping.

  • Others:

    Link to the original source: https://onlinelibrary.wiley.com/doi/10.1002/tcr.202300349
    APA: Fernández, E (2024). α-Boryl Carbanions: The Influence of Geminal Heteroatoms in C-C Bond Formation. Chemical Record, 24(3), e202300349-. DOI: 10.1002/tcr.202300349
    Paper original source: Chemical Record. 24 (3): e202300349-
    Article's DOI: 10.1002/tcr.202300349
    Journal publication year: 2024-03-01
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2026-05-09
    URV's Author/s: Fernández Gutiérrez, Maria Elena
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Fernández, E
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Medicine (miscellaneous), Materials chemistry, General chemistry, General chemical engineering, Engenharias ii, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Chemical engineering (miscellaneous), Chemical engineering (all), Biotecnología, Biochemistry (medical), Biochemistry
    Author's mail: mariaelena.fernandez@urv.cat, mariaelena.fernandez@urv.cat

  • Keywords:

    Α-thioboron carbanion
    Α-silicoboron carbanion
    Α-haloboron carbanion
    Α-boryl carbanion
    Α-aminoboron carbanion
    Stereoselective-synthesis
    Metal-free synthesis
    Gem-diborylalkanes
    Enantioselective synthesis
    Diborylmethan
    Catalyzed diborylation
    Carbonyl-compounds
    Boronic esters
    Asymmetric-synthesis
    Alpha-thioboron carbanion
    Alpha-silicoboron carbanion
    Alpha-haloboron carbanio
    Alpha-boryl carbanion
    Alpha-aminoboron carbanion
    Allylic substitution
    Biochemistry
    Biochemistry (Medical)
    Chemical Engineering (Miscellaneous)
    Chemistry (Miscellaneous)
    Chemistry
    Multidisciplinary
    Materials Chemistry
    Medicine (Miscellaneous)
    General chemistry
    General chemical engineering
    Engenharias ii
    Chemistry (all)
    Chemical engineering (all)
    Biotecnología

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