Author, as appears in the article.: Fernandez, Elena
Department: Química Física i Inorgànica
URV's Author/s: Fernández Gutiérrez, Maria Elena
Keywords: Allylic substitution Alpha-aminoboron carbanion Alpha-boryl carbanion Alpha-haloboron carbanio Alpha-silicoboron carbanion Alpha-thioboron carbanion Asymmetric-synthesis Boronic esters Carbonyl-compounds Catalyzed diborylation Diborylmethan Enantioselective synthesis Gem-diborylalkanes Metal-free synthesis Stereoselective-synthesis Α-aminoboron carbanion Α-boryl carbanion Α-haloboron carbanion Α-silicoboron carbanion Α-thioboron carbanion
Abstract: The wide applications of alpha-boryl carbanions in selective coupling with organohalides, imines/carbonyls and conjugated unsaturated substrates has become an interesting tool for organic synthesis. Strategically, the inclusion of heteroatoms, such as Si, S, N, F, Cl, Br and I in the alpha position opens a new venue towards multifunctionalities in molecular design. Here, a conceptual and practical view on powerful carbanions, containing alpha-silicoboron, alpha-thioboron, alpha-haloboron and alpha-aminoboron is given, as well as a prespective on their efficient application for selective electrophilic trapping.
Thematic Areas: Biochemistry Biochemistry (medical) Chemical engineering (all) Chemical engineering (miscellaneous) Chemistry (all) Chemistry (miscellaneous) Chemistry, multidisciplinary Ciência de alimentos Engenharias ii General chemical engineering General chemistry Materials chemistry Medicine (miscellaneous)
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: mariaelena.fernandez@urv.cat
Author identifier: 0000-0001-9025-1791
Record's date: 2025-02-18
Paper version: info:eu-repo/semantics/publishedVersion
Paper original source: Chemical Record. 24 (3): e202300349-
APA: Fernandez, Elena (2024). α-Boryl Carbanions: The Influence of Geminal Heteroatoms in C-C Bond Formation. Chemical Record, 24(3), e202300349-. DOI: 10.1002/tcr.202300349
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Entity: Universitat Rovira i Virgili
Journal publication year: 2024
Publication Type: Journal Publications
Repositori URV