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Asymmetrical flow field-flow fractionation hyphenated to Orbitrap high resolution mass spectrometry for the determination of (functionalised) aqueous fullerene aggregates

  • Datos identificativos

    Identificador: PC:1011
  • Autores:

    Herrero, P., Bäuerlein, P.S., Emke, E., Pocurull, E., de Voogt, P.
  • Otros:

    Autor según el artículo: Herrero, P., Bäuerlein, P.S., Emke, E., Pocurull, E., de Voogt, P.
    Departamento: Història i Història de l'Art
    Autor/es de la URV: P. Herrero, P.S. Bäuerlein, E. Emke, E. Pocurull, P. de Voogt
    Resumen: In this short communication we report on the technical implementations of coupling an asymmetric flow field-flow fractionation (AF4) instrument to a high resolution mass spectrometer (Orbitrap) using an atmospheric photoionisation interface. This will allow for the first time online identification of different fullerenes in aqueous samples after their aggregates have been fractionated in the FFF channel. Quality parameters such as limits of detection (LODs), limits of quantification (LOQs) or linear range were evaluated and they were in the range of hundreds ng/L for LODs and LOQs and the detector response was linear in the range tested (up to ~20. µg/L). The low detection and quantification limits make this technique useful for future environmental or ecotoxicology studies in which low concentration levels are expected for fullerenes and common on-line detectors such as UV or MALS do not have enough sensitivity and selectivity.
    Acceso a la licencia de uso:
    ISSN: 0021-9673
    Página final: 282
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original:
    DOI del artículo: 10.1016/j.chroma.2014.06.068
    Entidad: Universitat Rovira i Virgili.
    Año de publicación de la revista: 2014
    Página inicial: 277