Autor según el artículo: Cuesta-Aluja, L.; Castilla, J.; Masdeu-Bultó, A.M.; Henriques, C.A.; Calvete, M.J.F.; Pereira, M.M.

Departamento: Química Física i Inorgànica

Autor/es de la URV: CUESTA ALUJA, LAIA; Castilla, J.; MASDEU BULTÓ, ANNA MARIA; Henriques, C.A.; Calvete, M.J.F.; Pereira, M.M.

Palabras clave: metalloporphyrins cyclic carbonates polycarbonates

Resumen: Introduction of halogen electron withdrawing atoms (chloro and fluoro) in the ortho position of the aryl groups of meso-tetraphenylporphyrin manganese(III) complexes increased their activity as catalysts in the reaction of carbon dioxide with epoxides, when compared with the meso-tetraphenylporphyrin manganese(III) counterpart, even in the absence of co-catalysts. In the polymerization reaction of carbon dioxide and cyclohexene oxide, almost ten-fold increase of the TOF was observed when 5,10,15,20-tetra(2,6-dichlorophenyl)porphyrinatomanganese(III) acetate or 5,10,15,20-tetra(2,6 difluorophenyl)porphyrinatomanganese(III) acetate complexes were used as catalysts. Under similar conditions, when terminal epoxides were used as substrates, the selective cycloaddition of CO2 with styrene oxide, epichlorohydrin, propylene oxide, and 1,2-epoxytetradecane yielded exclusively the corresponding cyclic carbonates (conversion 54-98 %).

Grupo de investigación: Organometàl.lics i Catàlisi Homogènia

Áreas temáticas: Chemistry Química Química

Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 1381-1169

Identificador del autor: ; 0000-0003-1736-847X; ; n/a; 0000-0003-2094-4781; 0000-0003-4958-7677

Fecha de alta del registro: 2017-03-22

Página final: 494

Volumen de revista: 423

Versión del articulo depositado: info:eu-repo/semantics/submittedVersion

Enlace a la fuente original: http://www.sciencedirect.com/science/article/pii/S1381116915301291?via%3Dihub

DOI del artículo: 10.1016/j.molcata.2015.10.025

Entidad: Universitat Rovira i Virgili

Año de publicación de la revista: 2016

Página inicial: 489

Tipo de publicación: Article Artículo Article