Articles producció científica> Química Analítica i Química Orgànica

HPLC-UV and HPLC-CAD chromatographic data fusion for the authentication of the geographical origin of palm oil

  • Datos identificativos

    Identificador: PC:2802
    Autores:
    Ruisánchez, I.Obisesan, K.A.Jiménez-Carvelo, A.M.Cuadros-Rodriguez, L.Callao, M.P.
    Resumen:
    Filiació URV: SI
  • Otros:

    Autor según el artículo: Ruisánchez, I.; Obisesan, K.A.; Jiménez-Carvelo, A.M.; Cuadros-Rodriguez, L.; Callao, M.P.
    Departamento: Química Analítica i Química Orgànica
    Autor/es de la URV: RUISANCHEZ CAPELASTEGUI, MARÍA ICIAR; Obisesan, K.A.; Jiménez-Carvelo, A.M.; Cuadros-Rodriguez, L.; CALLAO LASMARIAS, MARÍA PILAR
    Palabras clave: authentication Data Fusion Liquid Chromatography
    Resumen: Data fusion combined with a multivariate classification approach (partial least squares-discriminant analysis, PLS-DA) was applied to authenticate the geographical origin of palm oil. Data fusion takes advantage of the synergistic effect of information collected from more than one data source. In this study, data from liquid chromatography coupled to two detectors –ultraviolet (UV) and charged aerosol (CAD)– was fused by high- and mid-level data fusion strategies. Mid-level data fusion combines a few variables from each technique and then applies the classification technique. Principal component analysis and interval partial least squares were applied to obtain the variables selected. High-level data fusion combines the PLS-DA classification results obtained individually from the chromatographic technique with each detector. Fuzzy aggregation connective operators were used to make the combinations. Prediction rates varied between 73% and 98% for the individual techniques and between 87% and 100% and 93% and 100% for the mid- and high-level data fusion strategies, respectively.
    Grupo de investigación: Grup de Quimiometria, Qualimetria i Nanosensors
    Áreas temáticas: Química Química Chemistry
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 0039-9140
    Identificador del autor: 0000-0002-7097-3583; n/a; n/a; n/a; 0000-0003-2691-329X
    Fecha de alta del registro: 2017-05-18
    Página final: 418
    Volumen de revista: 170
    Versión del articulo depositado: info:eu-repo/semantics/submittedVersion
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2017
    Página inicial: 413
    Tipo de publicación: Article Artículo Article
  • Palabras clave:

    Cromatografia de líquids
    authentication
    Data Fusion
    Liquid Chromatography
    Química
    Química
    Chemistry
    0039-9140
  • Documentos:

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