Autor según el artículo: Fernández, E. ; Cuenca, A. B. ; Shishido, R. ; Ito, H.

Departamento: Química Física i Inorgànica

Autor/es de la URV: FERNÁNDEZ GUTIÉRREZ, MARIA ELENA; Cuenca, A. B. ; Shishido, R. ; Ito, H.

Palabras clave: Transition-metal-free B-B activation modes

Resumen: This review is a guided tour along the activation modes and reactivity of B-B, B-Si, B-N, B-S, B-Se and B-P reagents, in the absence of any transition metal complex. Here are disclosed the general concepts related to the homolytic and heterolytic cleavage of the B-B and B-interelement bonds, as well as the generation of the new C-B and C-interelement bonds, in a selective way. The greener consequences of those novel routes facilitate the gram scale preparations of target functionalised organic compounds. Intrinsic data about the suggested mechanisms and spectroscopic evidences that support the innovative theories, are provided along the review. Since this is a stimulating area of work that has emerged within the last decade, this overview serves as the basis to understand the new trends and hopefully to generate inspiration for future discoveries in the field

Grupo de investigación: Organometàl.lics i Catàlisi Homogènia

Áreas temáticas: Chemistry Química Química

Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 0306-0012

Identificador del autor: 0000-0001-9025-1791; ; ;

Fecha de alta del registro: 2018-03-08

Página final: 30

Volumen de revista: 46

Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion

Enlace a la fuente original: http://pubs.rsc.org/en/Content/ArticleLanding/2017/CS/C6CS00692B#!divAbstract

DOI del artículo: 10.1039/c6cs00692b

Entidad: Universitat Rovira i Virgili

Año de publicación de la revista: 2017

Página inicial: 415

Tipo de publicación: Article Artículo Article