Articles producció científica> Enginyeria Química

Photodegradation of polycyclic aromatic hydrocarbons in soils under a climate change base scenario

  • Datos identificativos

    Identificador: imarina:2105272
    Autores:
    Marques, MontseMari, MontseAudi-Miro, CarmeSierra, JordiSoler, AlbertNadal, MartiDomingo, Jose L.
    Resumen:
    The photodegradation of polycyclic aromatic hydrocarbons (PAHs) in two typical Mediterranean soils, either coarse- or fine-textured, was here investigated. Soil samples, spiked with the 16 US EPA priority PAHs, were incubated in a climate chamber at stable conditions of temperature (20 °C) and light (9.6 W m(-2)) for 28 days, simulating a climate change base scenario. PAH concentrations in soils were analyzed throughout the experiment, and correlated with data obtained by means of Microtox(®) ecotoxicity test. Photodegradation was found to be dependent on exposure time, molecular weight of each hydrocarbon, and soil texture. Fine-textured soil was able to enhance sorption, being PAHs more photodegraded than in coarse-textured soil. According to the EC50 values reported by Microtox(®), a higher detoxification was observed in fine-textured soil, being correlated with the outcomes of the analytical study. Significant photodegradation rates were detected for a number of PAHs, namely phenanthrene, anthracene, benzo(a)pyrene, and indeno(123-cd)pyrene. Benzo(a)pyrene, commonly used as an indicator for PAH pollution, was completely removed after 7 days of light exposure. In addition to the PAH chemical analysis and the ecotoxicity tests, a hydrogen isotope analysis of benzo(a)pyrene was also carried out. The degradation of this specific compound was associated to a high enrichment in (2)H, obtaining a maximum ?(2)H isotopic shift of +232‰. This strong isotopic effect observed in benzo(a)pyrene suggests that compound-specific isotope analysis (CSIA) may be a powerful tool to monitor in situ degradation of PAHs. Moreover, hydrogen isotopes of benzo(a)pyrene evidenced a degradation process of unknown origin occurring in the darkness.Copyright © 2016 Elsevier Ltd. All rights reserv
  • Otros:

    Autor según el artículo: Marques, Montse; Mari, Montse; Audi-Miro, Carme; Sierra, Jordi; Soler, Albert; Nadal, Marti; Domingo, Jose L.;
    Departamento: Enginyeria Química Ciències Mèdiques Bàsiques
    Autor/es de la URV: Domingo Roig, José Luis / Mari Marcos, Montserrat / Marquès Bueno, Montserrat / Nadal Lomas, Martí
    Palabras clave: Water Uv-light Toxicity Soil Polycyclic aromatic hydrocarbons (pahs) Photolysis Photodegradation Photochemical degradation Photocatalytic degradation Pahs Organic pollutants Isotope fractionation Hydrogen isotopes Ecotoxicity Aqueous photodegradation polycyclic aromatic hydrocarbons (pahs) photodegradation hydrogen isotopes ecotoxicity
    Resumen: The photodegradation of polycyclic aromatic hydrocarbons (PAHs) in two typical Mediterranean soils, either coarse- or fine-textured, was here investigated. Soil samples, spiked with the 16 US EPA priority PAHs, were incubated in a climate chamber at stable conditions of temperature (20 °C) and light (9.6 W m(-2)) for 28 days, simulating a climate change base scenario. PAH concentrations in soils were analyzed throughout the experiment, and correlated with data obtained by means of Microtox(®) ecotoxicity test. Photodegradation was found to be dependent on exposure time, molecular weight of each hydrocarbon, and soil texture. Fine-textured soil was able to enhance sorption, being PAHs more photodegraded than in coarse-textured soil. According to the EC50 values reported by Microtox(®), a higher detoxification was observed in fine-textured soil, being correlated with the outcomes of the analytical study. Significant photodegradation rates were detected for a number of PAHs, namely phenanthrene, anthracene, benzo(a)pyrene, and indeno(123-cd)pyrene. Benzo(a)pyrene, commonly used as an indicator for PAH pollution, was completely removed after 7 days of light exposure. In addition to the PAH chemical analysis and the ecotoxicity tests, a hydrogen isotope analysis of benzo(a)pyrene was also carried out. The degradation of this specific compound was associated to a high enrichment in (2)H, obtaining a maximum ?(2)H isotopic shift of +232‰. This strong isotopic effect observed in benzo(a)pyrene suggests that compound-specific isotope analysis (CSIA) may be a powerful tool to monitor in situ degradation of PAHs. Moreover, hydrogen isotopes of benzo(a)pyrene evidenced a degradation process of unknown origin occurring in the darkness.Copyright © 2016 Elsevier Ltd. All rights reserved.
    Áreas temáticas: Zootecnia / recursos pesqueiros Saúde coletiva Química Public health, environmental and occupational health Pollution Odontología Nutrição Medicine (miscellaneous) Medicina veterinaria Medicina ii Medicina i Materiais Interdisciplinar Health, toxicology and mutagenesis Geociências General chemistry Farmacia Environmental sciences Environmental engineering Environmental chemistry Ensino Engenharias iii Engenharias ii Engenharias i Educação física Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry (miscellaneous) Chemistry (all) Biotecnología Biodiversidade Astronomia / física
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 00456535
    Direcció de correo del autor: joseluis.domingo@urv.cat marti.nadal@urv.cat montserrat.mari@urv.cat
    Identificador del autor: 0000-0001-6647-9470 0000-0002-0217-4827 0000-0001-8971-3856
    Fecha de alta del registro: 2024-09-07
    Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
    Enlace a la fuente original: https://www.sciencedirect.com/science/article/abs/pii/S0045653516300698?via%3Dihub
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Chemosphere. 148 (): 495-503
    Referencia de l'ítem segons les normes APA: Marques, Montse; Mari, Montse; Audi-Miro, Carme; Sierra, Jordi; Soler, Albert; Nadal, Marti; Domingo, Jose L.; (2016). Photodegradation of polycyclic aromatic hydrocarbons in soils under a climate change base scenario. Chemosphere, 148(), 495-503. DOI: 10.1016/j.chemosphere.2016.01.069
    DOI del artículo: 10.1016/j.chemosphere.2016.01.069
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2016
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Chemistry (Miscellaneous),Environmental Chemistry,Environmental Engineering,Environmental Sciences,Health, Toxicology and Mutagenesis,Medicine (Miscellaneous),Pollution,Public Health, Environmental and Occupational Health
    Water
    Uv-light
    Toxicity
    Soil
    Polycyclic aromatic hydrocarbons (pahs)
    Photolysis
    Photodegradation
    Photochemical degradation
    Photocatalytic degradation
    Pahs
    Organic pollutants
    Isotope fractionation
    Hydrogen isotopes
    Ecotoxicity
    Aqueous photodegradation
    polycyclic aromatic hydrocarbons (pahs)
    photodegradation
    hydrogen isotopes
    ecotoxicity
    Zootecnia / recursos pesqueiros
    Saúde coletiva
    Química
    Public health, environmental and occupational health
    Pollution
    Odontología
    Nutrição
    Medicine (miscellaneous)
    Medicina veterinaria
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    Health, toxicology and mutagenesis
    Geociências
    General chemistry
    Farmacia
    Environmental sciences
    Environmental engineering
    Environmental chemistry
    Ensino
    Engenharias iii
    Engenharias ii
    Engenharias i
    Educação física
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Chemistry (miscellaneous)
    Chemistry (all)
    Biotecnología
    Biodiversidade
    Astronomia / física
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