Autor según el artículo: Guo, Wusheng; Gomez, Jose Enrique; Martinez-Rodriguez, Luis; Bandeira, Nuno A. G.; Bo, Carles; Kleij, Arjan W.;
Departamento: Química Física i Inorgànica
Autor/es de la URV: Bo Jané, Carles
Palabras clave: Ring-opening aminolysis Organocatalysis N-aryl amides Lactones Aromatic amines organocatalysis n-aryl amides lactones aromatic amines
Resumen: Catalytic ring-opening of bio-sourced non-strained lactones with aromatic amines can offer a straightforward, 100% atom-economical, and sustainable pathway towards relevant N-aryl amide scaffolds. Herein, the first general, metal-free, and highly efficient N-aryl amide formation is reported from poorly reactive aromatic amines and non-strained lactones under mild operating conditions using an organic bicyclic guanidine catalyst. This protocol has high application potential as exemplified by the formal syntheses of drug-relevant molecules.
Áreas temáticas: Química Materials science (miscellaneous) Materials science (all) Materiais Interdisciplinar Green & sustainable science & technology General materials science General energy General chemical engineering Farmacia Environmental chemistry Engenharias iii Engenharias ii Energy (miscellaneous) Energy (all) Chemistry, multidisciplinary Chemical engineering (miscellaneous) Chemical engineering (all) Biotecnología Astronomia / física
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
Direcció de correo del autor: carles.bo@urv.cat
Identificador del autor: 0000-0001-9581-2922
Fecha de alta del registro: 2024-09-07
Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
Enlace a la fuente original: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.201700415
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Chemsuschem. 10 (9): 1969-1975
Referencia de l'ítem segons les normes APA: Guo, Wusheng; Gomez, Jose Enrique; Martinez-Rodriguez, Luis; Bandeira, Nuno A. G.; Bo, Carles; Kleij, Arjan W.; (2017). Metal‐Free Synthesis of N‐Aryl Amides using Organocatalytic Ring‐Opening Aminolysis of Lactones. Chemsuschem, 10(9), 1969-1975. DOI: 10.1002/cssc.201700415
DOI del artículo: 10.1002/cssc.201700415
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2017
Tipo de publicación: Journal Publications
Repositori URV