Autor según el artículo: Kasetaite S, De la Flor S, Serra A, Ostrauskaite J.

Departamento: Química Analítica i Química Orgànica Enginyeria Mecànica

e-ISSN: 2073-4360

Autor/es de la URV: De la Flor Lopez, Silvia / Serra Albet, Maria Angels

Palabras clave: Thiol–michael Thiol-michael Thiol Thermosets Soybean oil Renewable resources Michael addition Cross-linking Boron nitride Bio-based polymer soybean oil cross-linking bio-based polymer

Resumen: The effect of the chemical structure and functionality of three structurally different thiols on the cross-linking of acrylated epoxidized soybean oil and on the properties of the resulting polymers was investigated in this study. 1,3-Benzenedithiol, pentaerythritol tetra(3-mercaptopropionate), and an hexathiol synthesized from squalene were used in the cross-linking of acrylated epoxidized soybean oil by thiol¿Michael addition reaction. The reactivity of thiols determined from calorimetric curves followed the order: 1,3-benzenedithiol > pentaerythritol tetra(3-mercaptopropionate) > hexathiolated squalene. Thermal and mechanical properties and the swelling in different solvents of the cross-linked polymers were studied. The cross-linked polymer obtained from 1,3-benzenedithiol showed the highest swelling values in chloroform and toluene. The cross-linked polymer with pentaerythritol tetra(3-mercaptopropionate) fragments showed the best mechanical performance (highest mechanical strength and Young¿s modulus) and thermal stability. The cross-linked polymers from hexathiolated squalene showed the highest glass transition temperature.

Áreas temáticas: Polymers and plastics Polymer science Odontología General chemistry Farmacia Engenharias ii Ciências biológicas ii Chemistry (miscellaneous) Chemistry (all) Biotecnología Astronomia / física

Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 20734360

Direcció de correo del autor: silvia.delaflor@urv.cat angels.serra@urv.cat

Identificador del autor: 0000-0002-6851-1371 0000-0003-1387-0358

Fecha de alta del registro: 2023-02-18

Volumen de revista: 10

Versión del articulo depositado: info:eu-repo/semantics/publishedVersion

Enlace a la fuente original: https://www.mdpi.com/2073-4360/10/4/439

URL Documento de licencia: http://repositori.urv.cat/ca/proteccio-de-dades/

Referencia al articulo segun fuente origial: Polymers. 10 (4):

Referencia de l'ítem segons les normes APA: Kasetaite S, De la Flor S, Serra A, Ostrauskaite J. (2018). Effect of Selected Thiols on Cross-linking of Acrylated Epoxidized Soybean Oil and Properties of Resulting Polymers. Polymers, 10(4), -. DOI: 10.3390/polym10040439

DOI del artículo: 10.3390/polym10040439

Entidad: Universitat Rovira i Virgili

Año de publicación de la revista: 2018

Página inicial: 439

Tipo de publicación: Journal Publications