Autor según el artículo: Pinos-Velez, Veronica; di Luca, Carla; Crivoi, Dana G.; Medina, Francisco; Dafinov, Anton;

Departamento: Enginyeria Química

Autor/es de la URV: Dafinov, Anton Ivanov / Medina Cabello, Francisco

Palabras clave: Wet air oxidation Phenol Performance Nanoparticles Microemulsion Hydrogen-peroxide H2o2

Resumen: Several procedures were employed in the preparation of different Pd- and Fe-based catalytic membrane reactors (CMRs) via the normal wet impregnation method, reverse filtration of a microemulsion, sputtering method, and the precipitation of a Fe complex. Depending on the chosen procedure, the metal active phase can be found on the exterior and/or interior part of the CMR or even in its pores in concentrations between 0.05 and 2 wt %. Moreover, we have managed to implement a unique systematic process to grow hydrotalcite in the pores of a Pd-CMR. To exemplify the activity of these new CMRs, we have tested them in the peroxidation of phenol and in situ epoxidation of trans-chalcone.

Áreas temáticas: Química Interdisciplinar General chemistry General chemical engineering Engenharias ii Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemical engineering (miscellaneous) Chemical engineering (all)

Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 24701343

Direcció de correo del autor: francesc.medina@urv.cat anton.dafinov@urv.cat anton.dafinov@urv.cat

Identificador del autor: 0000-0002-3111-1542 0000-0002-6124-3095 0000-0002-6124-3095

Fecha de alta del registro: 2023-02-22

Versión del articulo depositado: info:eu-repo/semantics/publishedVersion

Enlace a la fuente original: https://pubs.acs.org/doi/10.1021/acsomega.9b02706

URL Documento de licencia: http://repositori.urv.cat/ca/proteccio-de-dades/

Referencia al articulo segun fuente origial: Acs Omega. 4 (22): 19818-19828

Referencia de l'ítem segons les normes APA: Pinos-Velez, Veronica; di Luca, Carla; Crivoi, Dana G.; Medina, Francisco; Dafinov, Anton; (2019). Catalytic Palladium-Based and Iron-Based Membrane Reactors: Novel Strategies of Synthesis. Acs Omega, 4(22), 19818-19828. DOI: 10.1021/acsomega.9b02706

DOI del artículo: 10.1021/acsomega.9b02706

Entidad: Universitat Rovira i Virgili

Año de publicación de la revista: 2019

Tipo de publicación: Journal Publications