Autor según el artículo: Salvadó O; Fernández E

Departamento: Química Física i Inorgànica

Autor/es de la URV: Fernández Gutiérrez, Maria Elena

Palabras clave: Terminal alkynes Synthetic approaches Synthetic applications Ketones Esters Diboration Construction Borylation Alkylation Aldehydes 1,2,3-tri(boryl)alkanes 1,1,2-tri(boryl)alkanes 1,1,2-tri(boryl) alkenes 1,1,1-tri(boryl)alkanes synthetic applications 1,2,3-tri(boryl)alkanes 1,1,2-tri(boryl)alkenes 1,1,2-tri(boryl)alkanes 1,1,1-tri(boryl)alkanes

Resumen: © 2020 by the authors. The interest of organoboron chemistry in organic synthesis is growing, together with the development of new and versatile polyborated reagents. Here, the preparation of 1,1,1-tri(boryl)alkanes, 1,2,3-tri(boryl)alkanes, 1,1,2-tri(boryl)alkanes, as well as 1,1,2-tri(boryl)alkenes as suitable and accessible polyborated systems is demonstrated as being easily applied in the construction of new carbon-carbon and carbon-heteroatom bonds. Synthetic procedures and limitations have been collected to demonstrate the powerful strategies to construct selective molecules, taking advantages of the easy transformation of carbon-boron bond in multiple functionalities, under the total control of chemo- and stereoselectivity.

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Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 14203049

Direcció de correo del autor: mariaelena.fernandez@urv.cat

Identificador del autor: 0000-0001-9025-1791

Fecha de alta del registro: 2023-02-19

Versión del articulo depositado: info:eu-repo/semantics/publishedVersion

Enlace a la fuente original: https://www.mdpi.com/1420-3049/25/7/1758

URL Documento de licencia: http://repositori.urv.cat/ca/proteccio-de-dades/

Referencia al articulo segun fuente origial: Molecules. 25 (7):

Referencia de l'ítem segons les normes APA: Salvadó O; Fernández E (2020). Tri(boryl)alkanes and tri(boryl)alkenes: The versatile reagents. Molecules, 25(7), -. DOI: 10.3390/molecules25071758

DOI del artículo: 10.3390/molecules25071758

Entidad: Universitat Rovira i Virgili

Año de publicación de la revista: 2020

Tipo de publicación: Journal Publications