Autor según el artículo: Salvadó O; Fernández E
Departamento: Química Física i Inorgànica
Autor/es de la URV: Fernández Gutiérrez, Maria Elena / Fernández López, Elena / Salvadó Ruiz, Oriol
Palabras clave: Terminal alkynes Synthetic approaches Synthetic applications Ketones Esters Diboration Construction Borylation Alkylation Aldehydes 1,2,3-tri(boryl)alkanes 1,1,2-tri(boryl)alkanes 1,1,2-tri(boryl) alkenes 1,1,1-tri(boryl)alkanes synthetic applications 1,2,3-tri(boryl)alkanes 1,1,2-tri(boryl)alkenes 1,1,2-tri(boryl)alkanes 1,1,1-tri(boryl)alkanes
Resumen: © 2020 by the authors. The interest of organoboron chemistry in organic synthesis is growing, together with the development of new and versatile polyborated reagents. Here, the preparation of 1,1,1-tri(boryl)alkanes, 1,2,3-tri(boryl)alkanes, 1,1,2-tri(boryl)alkanes, as well as 1,1,2-tri(boryl)alkenes as suitable and accessible polyborated systems is demonstrated as being easily applied in the construction of new carbon-carbon and carbon-heteroatom bonds. Synthetic procedures and limitations have been collected to demonstrate the powerful strategies to construct selective molecules, taking advantages of the easy transformation of carbon-boron bond in multiple functionalities, under the total control of chemo- and stereoselectivity.
Áreas temáticas: Zootecnia / recursos pesqueiros Saúde coletiva Química Psicología Planejamento urbano e regional / demografia Physical and theoretical chemistry Pharmaceutical science Organic chemistry Odontología Nutrição Molecular medicine Medicine (miscellaneous) Medicina veterinaria Medicina iii Medicina ii Medicina i Materiais Matemática / probabilidade e estatística Interdisciplinar Geografía General medicine Farmacia Ensino Engenharias iv Engenharias iii Engenharias ii Engenharias i Educação física Economia Drug discovery Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Ciência da computação Chemistry, organic Chemistry, multidisciplinary Chemistry (miscellaneous) Biotecnología Biodiversidade Biochemistry & molecular biology Astronomia / física Analytical chemistry
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 14203049
Direcció de correo del autor: oriol.salvado@urv.cat mariaelena.fernandez@urv.cat
Identificador del autor: 0000-0001-9025-1791
Fecha de alta del registro: 2024-10-26
Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
Enlace a la fuente original: https://www.mdpi.com/1420-3049/25/7/1758
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Molecules. 25 (7):
Referencia de l'ítem segons les normes APA: Salvadó O; Fernández E (2020). Tri(boryl)alkanes and tri(boryl)alkenes: The versatile reagents. Molecules, 25(7), -. DOI: 10.3390/molecules25071758
DOI del artículo: 10.3390/molecules25071758
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2020
Tipo de publicación: Journal Publications