Articles producció científica> Química Física i Inorgànica

Evolution of phosphorus-thioether ligands for asymmetric catalysis

  • Datos identificativos

    Identificador: imarina:8680274
    Autores:
    Margalef JPàmies OPericàs MADiéguez M
    Resumen:
    © The Royal Society of Chemistry 2020. In the early 1990s chiral P-thiother ligands emerged as promising ligands in the field of asymmetric catalysis, with the development of many P-thioether ligand families. However, only a few of them have shown a broad reaction and substrate scope. So, compared with other heterodonor ligands such as the widely studied P-N ligands, their impact in asymmetric catalysis was not realised until recently. This has been mainly attributed to the difficulty of controlling the configuration at the sulfur atom when coordinated to the metal. More recently, it has been found that this problem could be solved by a rigorous choice of the ligand scaffold, a process usually aided by mechanistic studies. This allowed the recent discovery of new P-thioether ligand families with a broader versatility, both in reactions and in substrate/reagent scope. This feature article aims to highlight those new P-thioether ligand libraries and the relationship between the structure and catalytic performance.
  • Otros:

    Autor según el artículo: Margalef J; Pàmies O; Pericàs MA; Diéguez M
    Departamento: Química Física i Inorgànica
    Autor/es de la URV: Diéguez Fernández, Montserrat / Margalef Pallarès, Jèssica / Pamies Ollé, Oscar
    Palabras clave: Planar chiral ligands Phosphite-oxazoline ligands Minimally functionalized olefins Mannich reaction Glycine imino ester Diels-alder reaction Cyclic beta-enamides Azomethine ylides Allylic alkylation 1,3-dipolar cycloaddition
    Resumen: © The Royal Society of Chemistry 2020. In the early 1990s chiral P-thiother ligands emerged as promising ligands in the field of asymmetric catalysis, with the development of many P-thioether ligand families. However, only a few of them have shown a broad reaction and substrate scope. So, compared with other heterodonor ligands such as the widely studied P-N ligands, their impact in asymmetric catalysis was not realised until recently. This has been mainly attributed to the difficulty of controlling the configuration at the sulfur atom when coordinated to the metal. More recently, it has been found that this problem could be solved by a rigorous choice of the ligand scaffold, a process usually aided by mechanistic studies. This allowed the recent discovery of new P-thioether ligand families with a broader versatility, both in reactions and in substrate/reagent scope. This feature article aims to highlight those new P-thioether ligand libraries and the relationship between the structure and catalytic performance.
    Áreas temáticas: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 13597345
    Direcció de correo del autor: montserrat.dieguez@urv.cat oscar.pamies@urv.cat
    Identificador del autor: 0000-0002-8450-0656 0000-0002-2352-8508
    Fecha de alta del registro: 2023-12-16
    Versión del articulo depositado: info:eu-repo/semantics/submittedVersion
    Enlace a la fuente original: https://pubs.rsc.org/en/content/articlelanding/2020/cc/d0cc04145a
    Referencia al articulo segun fuente origial: Chemical Communications. 56 (74): 10795-10808
    Referencia de l'ítem segons les normes APA: Margalef J; Pàmies O; Pericàs MA; Diéguez M (2020). Evolution of phosphorus-thioether ligands for asymmetric catalysis. Chemical Communications, 56(74), 10795-10808. DOI: 10.1039/d0cc04145a
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    DOI del artículo: 10.1039/d0cc04145a
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2020
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Catalysis,Ceramics and Composites,Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary,Electronic, Optical and Magnetic Materials,Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films
    Planar chiral ligands
    Phosphite-oxazoline ligands
    Minimally functionalized olefins
    Mannich reaction
    Glycine imino ester
    Diels-alder reaction
    Cyclic beta-enamides
    Azomethine ylides
    Allylic alkylation
    1,3-dipolar cycloaddition
    Surfaces, coatings and films
    Química
    Metals and alloys
    Medicina ii
    Medicina i
    Materials chemistry
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Electronic, optical and magnetic materials
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Ceramics and composites
    Catalysis
    Biotecnología
    Biodiversidade
    Astronomia / física
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