Autor según el artículo: Cuenca AB; Fernández E
Departamento: Química Física i Inorgànica
e-ISSN: 1460-4744
Autor/es de la URV: Fernández Gutiérrez, Maria Elena
Palabras clave: Stereoselective-synthesis Ketones Generation Esters Deprotonation Carbonyl-compounds Carbanions Bis(ethylenedioxyboryl)methide Aldehydes
Resumen: © The Royal Society of Chemistry. The condensation of easy manageable lithium α-bis(boryl)carbanions with carbonyl derivatives, the so-called boron-Wittig reaction, allows for the straightforward and often stereoselective formation of synthetically highly versatile metalloid-substituted alkenes, which are key building blocks on route to all-carbon substituted olefins. In this Tutorial review the concept behind this olefination reaction and its application to ketones, aldehydes and other carbonyl derivatives, such amides, ester and carboxylic acids, are presented in a systematic manner. A special emphasis has been placed on parameters controlling the stereochemical outcome of these transformations. To illustrate the great synthetic potential of this new methodological tool, a section is also included covering a selection of applications of the boron-Wittig reaction to target compounds via subsequent C-C bond-forming process. This journal is
Áreas temáticas: Química Materiais General medicine General chemistry Ciências biológicas ii Ciência de alimentos Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Antropologia / arqueologia
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 0306-0012
Direcció de correo del autor: mariaelena.fernandez@urv.cat
Identificador del autor: 0000-0001-9025-1791
Fecha de alta del registro: 2024-07-27
Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
Enlace a la fuente original: https://pubs.rsc.org/en/content/articlelanding/2021/cs/d0cs00953a#!divAbstract
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Chemical Society Reviews. 50 (1): 72-86
Referencia de l'ítem segons les normes APA: Cuenca AB; Fernández E (2021). Boron-Wittig olefination with: Gem -bis(boryl)alkanes. Chemical Society Reviews, 50(1), 72-86. DOI: 10.1039/d0cs00953a
DOI del artículo: 10.1039/d0cs00953a
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2021
Tipo de publicación: Journal Publications