Autor según el artículo: Margalef, Jessica; Biosca, Maria; de la Cruz Sanchez, Pol; Faiges, Jorge; Pamies, Oscar; Dieguez, Montserrat;

Departamento: Química Física i Inorgànica

Autor/es de la URV: Biosca Brull, Maria / De la Cruz Sánchez Badia, Pol / Diéguez Fernández, Montserrat / Faiges Marcos, Jorge / Margalef Pallarès, Jèssica / Pamies Ollé, Oscar

Palabras clave: Transition-metal-complexes Selective 1,1-binaphthyl synthesis Phosphorus-containing oxazoline Phosphite-oxazoline ligands P-s ligands P-o ligands P-n ligands Minimally functionalized olefins Ligand design Enantioselective total-synthesis Diastereoselective mannich reaction Atropisomeric phosphinamine ligand Asymmetric catalysis Alpha,beta-unsaturated carboxylic-acids Allylic substitution-reactions

Resumen: The success of phosphine-oxazoline ligands (PHOX) inspired the progress in P-oxazoline ligand families by modifying either the ligand backbone, the electronic and/or steric properties of the phosphine group or by exchanging the phosphine to a phosphinite or a phosphite group. In this respect, the structures of chiral P-oxazoline ligands have become more diverse and new families of very efficient ligands have emerged, which have improved catalytic performance in some asymmetric transformations, with an increased versatility, both in the range of reactions and in the range of substrates/reagents. In addition, most of ligands are synthesized from easily accessible chiral amino alcohols, maintaining the short and efficient synthetic route developed for PHOX ligands. New ligands have been developed by replacing the oxazoline functionality with several other N-donor groups, e.g. imidazole, thiazole, oxazole, pyridine, etc., and O- and S-groups. This review offers a critical overview of the utility of these most successful bidentate heterodonor P-N, P-O and P-S ligand families applied in metal-mediated processes. We illustrate how, through proper ligand design, these heterodonor bidentate ligand families can be an excellent source of ligands, with superior catalytic performance in many asymmetric reactions than the best C-2-symmetric N,N and P,P-ligands reported so far. (C) 2021 The Authors. Published by Elsevier B.V.

Áreas temáticas: Química Physical and theoretical chemistry Medicina ii Materials chemistry Materiais Interdisciplinar Inorganic chemistry General chemistry Farmacia Engenharias iv Ciências biológicas ii Chemistry, inorganic & nuclear Chemistry (miscellaneous) Chemistry (all) Biotecnología Astronomia / física

Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/

Direcció de correo del autor: pol.delacruzsanchez@urv.cat jorge.faiges@urv.cat maria.biosca@urv.cat montserrat.dieguez@urv.cat oscar.pamies@urv.cat jorge.faiges@urv.cat pol.delacruzsanchez@urv.cat

Identificador del autor: 0000-0002-9116-6318 0000-0002-8450-0656 0000-0002-2352-8508

Fecha de alta del registro: 2023-08-05

Versión del articulo depositado: info:eu-repo/semantics/publishedVersion

Enlace a la fuente original: https://www.sciencedirect.com/science/article/pii/S0010854521003945

URL Documento de licencia: http://repositori.urv.cat/ca/proteccio-de-dades/

Referencia al articulo segun fuente origial: Coordination Chemistry Reviews. 446

Referencia de l'ítem segons les normes APA: Margalef, Jessica; Biosca, Maria; de la Cruz Sanchez, Pol; Faiges, Jorge; Pamies, Oscar; Dieguez, Montserrat; (2021). Evolution in heterodonor P-N, P-S and P-O chiral ligands for preparing efficient catalysts for asymmetric catalysis. From design to applications. Coordination Chemistry Reviews, 446(), -. DOI: 10.1016/j.ccr.2021.214120

DOI del artículo: 10.1016/j.ccr.2021.214120

Entidad: Universitat Rovira i Virgili

Año de publicación de la revista: 2021

Tipo de publicación: Journal Publications