Articles producció científica> Química Física i Inorgànica

N=N Bond Cleavage by Tantalum Hydride Complexes: Mechanistic Insights and Reactivity

  • Datos identificativos

    Identificador: imarina:9242328
    Autores:
    Álvarez-Ruiz ECarbó JJGómez MHernández-Prieto CHernán-Gómez AMartín AMena MRicart JMSalom-Català ASantamaría C
    Resumen:
    The reaction of [TaCpRX4] (CpR = ?5-C5Me5, ?5-C5H4SiMe3, ?5-C5HMe4; X = Cl, Br) with SiH3Ph resulted in the formation of the dinuclear hydride tantalum(IV) compounds [(TaCpRX2)2(?-H)2], structurally identified by single-crystal X-ray analyses. These species react with azobenzene to give the mononuclear imide complex [TaCpRX2(NPh)] along with the release of molecular hydrogen. Analogous reactions between the [{Ta(?5-C5Me5)X2}2(?-H)2] derivatives and the cyclic diazo reagent benzo[c]cinnoline afford the biphenyl-bridged (phenylimido)tantalum complexes [{Ta(?5-C5Me5)X2}2(?-NC6H4C6H4N)] along with the release of molecular hydrogen. When the compounds [(TaCpRX2)2(?-H)2] (CpR = ?5-C5H4SiMe3, ?5-C5HMe4; X = Cl, Br) were employed, we were able to trap the side-on-bound diazo derivatives [(TaCpRX)2{?-(?2,?2-NC6H4C6H4N)}] (CpR = ?5-C5H4SiMe3, ?5-C5HMe4; X = Cl, Br) as intermediates in the N=N bond cleavage process. DFT calculations provide insights into the N=N cleavage mechanism, in which the ditantalum(IV) fragment can promote two-electron reductions of the N=N bond at two different metal-metal bond splitting stages. © 2021 The Authors. Published by American Chemical Society.
  • Otros:

    Autor según el artículo: Álvarez-Ruiz E; Carbó JJ; Gómez M; Hernández-Prieto C; Hernán-Gómez A; Martín A; Mena M; Ricart JM; Salom-Català A; Santamaría C
    Departamento: Química Física i Inorgànica
    Autor/es de la URV: Carbó Martin, Jorge Juan / Ricart Pla, Jose Manuel
    Palabras clave: Early transition-metals potential basis-sets polarization functions nitrogen molecular-orbital methods hydrogenation effective core potentials dinitrogen activation crystal-structure coordination basis-sets azobenzene ab-initio
    Resumen: The reaction of [TaCpRX4] (CpR = ?5-C5Me5, ?5-C5H4SiMe3, ?5-C5HMe4; X = Cl, Br) with SiH3Ph resulted in the formation of the dinuclear hydride tantalum(IV) compounds [(TaCpRX2)2(?-H)2], structurally identified by single-crystal X-ray analyses. These species react with azobenzene to give the mononuclear imide complex [TaCpRX2(NPh)] along with the release of molecular hydrogen. Analogous reactions between the [{Ta(?5-C5Me5)X2}2(?-H)2] derivatives and the cyclic diazo reagent benzo[c]cinnoline afford the biphenyl-bridged (phenylimido)tantalum complexes [{Ta(?5-C5Me5)X2}2(?-NC6H4C6H4N)] along with the release of molecular hydrogen. When the compounds [(TaCpRX2)2(?-H)2] (CpR = ?5-C5H4SiMe3, ?5-C5HMe4; X = Cl, Br) were employed, we were able to trap the side-on-bound diazo derivatives [(TaCpRX)2{?-(?2,?2-NC6H4C6H4N)}] (CpR = ?5-C5H4SiMe3, ?5-C5HMe4; X = Cl, Br) as intermediates in the N=N bond cleavage process. DFT calculations provide insights into the N=N cleavage mechanism, in which the ditantalum(IV) fragment can promote two-electron reductions of the N=N bond at two different metal-metal bond splitting stages. © 2021 The Authors. Published by American Chemical Society.
    Áreas temáticas: Química Physical and theoretical chemistry Medicina i Materiais Interdisciplinar Inorganic chemistry General medicine Farmacia Engenharias iii Engenharias ii Engenharias i Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Chemistry, inorganic & nuclear Chemistry (miscellaneous) Biotecnología Astronomia / física
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: j.carbo@urv.cat josep.ricart@urv.cat
    Identificador del autor: 0000-0002-3945-6721 0000-0002-2610-5535
    Fecha de alta del registro: 2024-09-07
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original: https://pubs.acs.org/doi/10.1021/acs.inorgchem.1c03152
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Inorganic Chemistry. 61 (1): 474-485
    Referencia de l'ítem segons les normes APA: Álvarez-Ruiz E; Carbó JJ; Gómez M; Hernández-Prieto C; Hernán-Gómez A; Martín A; Mena M; Ricart JM; Salom-Català A; Santamaría C (2022). N=N Bond Cleavage by Tantalum Hydride Complexes: Mechanistic Insights and Reactivity. Inorganic Chemistry, 61(1), 474-485. DOI: 10.1021/acs.inorgchem.1c03152
    DOI del artículo: 10.1021/acs.inorgchem.1c03152
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2022
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Chemistry (Miscellaneous),Chemistry, Inorganic & Nuclear,Inorganic Chemistry,Physical and Theoretical Chemistry
    Early transition-metals
    potential basis-sets
    polarization functions
    nitrogen
    molecular-orbital methods
    hydrogenation
    effective core potentials
    dinitrogen activation
    crystal-structure
    coordination
    basis-sets
    azobenzene
    ab-initio
    Química
    Physical and theoretical chemistry
    Medicina i
    Materiais
    Interdisciplinar
    Inorganic chemistry
    General medicine
    Farmacia
    Engenharias iii
    Engenharias ii
    Engenharias i
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Chemistry, inorganic & nuclear
    Chemistry (miscellaneous)
    Biotecnología
    Astronomia / física
  • Documentos:

  • Cerca a google

    Search to google scholar