Autor según el artículo: Demir-Duz, Hande; Perez-Estrada, Leonidas A; Alvarez, Mayra G; El-Din, Mohamed Gamal; Contreras, Sandra
Departamento: Enginyeria Química
Autor/es de la URV: Contreras Iglesias, Sandra / GARCÍA ALVAREZ, MAYRA
Palabras clave: Water treatment Water purification Water pollutants, chemical Water Ozone Ospw Oil and gas fields Naphthenic acids Hydrogen peroxide Electrical energy per order Carboxylic acids Advanced oxidation processes water treatment waste-water toxicity peroxide performance ozone ozonation naphthenic acids electrical energy per order degradation advanced oxidation processes
Resumen: The oil sands industry generates large volumes of oil sands process water (OSPW). There is an urgent need for OSPW treatment to reduce process water inventories and to support current reclamation approaches. This study discusses how efficient ozone (O3)-based combined advanced oxidation processes (AOPs), including hydrogen peroxide (H2O2) and UV-C, are at achieving mineralization while reducing the toxicity arising from such organic components as naphthenic acids (NAs) in OSPW. The results showed that the dissolved organic carbon (DOC) removals of 45%, 84%, 84% and 98%, obtained after 90-min treatments with O3, O3/H2O2, UVC/O3 and UVC/O3/H2O2, respectively, at a production rate of 6 g/L·h O3 were considerably higher than at lower O3 production rates. The acute toxicity on Vibrio fischeri was significantly reduced by all the treatments, which explains the high percentages of NA removal (up to 99% as confirmed by UPLC-QTOF-HRMS.) Mineralization (expressed as DOC removal) was highest with UVC/O3/H2O2 at ca. 2 mg C/L in the treated effluent, which means that it could be used as cooling/boiling process water in bitumen upgrading units. However, considering the energy demand of the treatments tested, the treatment using O3/H2O2 was found to be the most realistic for large-scale applications.
Áreas temáticas: Zootecnia / recursos pesqueiros Waste management and disposal Saúde coletiva Química Pollution Odontología Nutrição Medicina veterinaria Medicina iii Medicina ii Medicina i Materiais Matemática / probabilidade e estatística Interdisciplinar Historia Geografía Geociências Farmacia Environmental sciences Environmental engineering Environmental chemistry Ensino Engenharias iii Engenharias ii Engenharias i Enfermagem Direito Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Ciência da computação Biotecnología Biodiversidade Astronomia / física
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
Direcció de correo del autor: sandra.contreras@urv.cat
Identificador del autor: 0000-0001-8917-4733
Fecha de alta del registro: 2024-10-12
Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
Enlace a la fuente original: https://www.sciencedirect.com/science/article/pii/S0048969722018976
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Science Of The Total Environment. 832 154804-
Referencia de l'ítem segons les normes APA: Demir-Duz, Hande; Perez-Estrada, Leonidas A; Alvarez, Mayra G; El-Din, Mohamed Gamal; Contreras, Sandra (2022). O3/H2O2 and UV-C light irradiation treatment of oil sands process water. Science Of The Total Environment, 832(), 154804-. DOI: 10.1016/j.scitotenv.2022.154804
DOI del artículo: 10.1016/j.scitotenv.2022.154804
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2022
Tipo de publicación: Journal Publications
Repositori URV