Articles producció científica> Química Analítica i Química Orgànica

RDRP (Meth)acrylic Homo and Block Polymers from Lignocellulosic Sugar Derivatives

  • Datos identificativos

    Identificador: imarina:9261782
    Autores:
    Pala, MarcWoods, Sarah E.Hatton, Fiona L.Lligadas, Gerard
    Resumen:
    Currently, most commodity chemicals and polymers are manufactured from nonrenewable petroleum-based resources. However, due to its finite nature and social claims about environment preservation, alternative sources of value-added and building block chemicals are being intensively studied. Renewable lignocellulosic biomass has offered an attractive replacement for fossil-based chemicals. Lignin and C5/C6 sugars obtained from lignocellulosic biomass through chemical and enzymatic methods can be further transformed to targeted chemical platforms. In the present review, synthetic pathways for well-defined poly(meth)acrylates obtained from C5/C6 sugar-derived platforms in which the sugar structure is not retained are discussed. While bio-based polymers from these monomers are investigated using a wide range of polymerization techniques, this study focuses on precise synthesis of macromolecular structures taking advantage of reversible-deactivation radical polymerization methods and their applications.
  • Otros:

    Autor según el artículo: Pala, Marc; Woods, Sarah E.; Hatton, Fiona L.; Lligadas, Gerard;
    Departamento: Química Analítica i Química Orgànica
    Autor/es de la URV: Lligadas Puig, Gerard / PALÀ SÁNCHEZ, MARC
    Palabras clave: Transfer radical polymerization Thermoplastic elastomers Sterically hindered monomers Renewable resources Raft polymerization Mesoporous silica nanoparticles Lignocellulose Fragmentation chain transfer Ethyl lactate Diels-alder reaction Controlled radical polymerization Block polymers Bio-based chemicals Aba triblock copolymer
    Resumen: Currently, most commodity chemicals and polymers are manufactured from nonrenewable petroleum-based resources. However, due to its finite nature and social claims about environment preservation, alternative sources of value-added and building block chemicals are being intensively studied. Renewable lignocellulosic biomass has offered an attractive replacement for fossil-based chemicals. Lignin and C5/C6 sugars obtained from lignocellulosic biomass through chemical and enzymatic methods can be further transformed to targeted chemical platforms. In the present review, synthetic pathways for well-defined poly(meth)acrylates obtained from C5/C6 sugar-derived platforms in which the sugar structure is not retained are discussed. While bio-based polymers from these monomers are investigated using a wide range of polymerization techniques, this study focuses on precise synthesis of macromolecular structures taking advantage of reversible-deactivation radical polymerization methods and their applications.
    Áreas temáticas: Química Polymers and plastics Polymer science Physical and theoretical chemistry Organic chemistry Materials chemistry Materiais Engenharias ii Condensed matter physics
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: marc.pala@urv.cat marc.pala@urv.cat gerard.lligadas@urv.cat
    Identificador del autor: 0000-0002-8519-1840
    Fecha de alta del registro: 2024-09-07
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original: https://onlinelibrary.wiley.com/doi/10.1002/macp.202200005
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Macromolecular Chemistry And Physics. 223 (13):
    Referencia de l'ítem segons les normes APA: Pala, Marc; Woods, Sarah E.; Hatton, Fiona L.; Lligadas, Gerard; (2022). RDRP (Meth)acrylic Homo and Block Polymers from Lignocellulosic Sugar Derivatives. Macromolecular Chemistry And Physics, 223(13), -. DOI: 10.1002/macp.202200005
    DOI del artículo: 10.1002/macp.202200005
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2022
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Condensed Matter Physics,Materials Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Polymer Science,Polymers and Plastics
    Transfer radical polymerization
    Thermoplastic elastomers
    Sterically hindered monomers
    Renewable resources
    Raft polymerization
    Mesoporous silica nanoparticles
    Lignocellulose
    Fragmentation chain transfer
    Ethyl lactate
    Diels-alder reaction
    Controlled radical polymerization
    Block polymers
    Bio-based chemicals
    Aba triblock copolymer
    Química
    Polymers and plastics
    Polymer science
    Physical and theoretical chemistry
    Organic chemistry
    Materials chemistry
    Materiais
    Engenharias ii
    Condensed matter physics
  • Documentos:

  • Cerca a google

    Search to google scholar