Articles producció científica> Enginyeria Química

Comparative Study of Sonophotocatalytic, Photocatalytic, and Catalytic Activities of Magnesium and Chitosan-Doped Tin Oxide Quantum Dots

  • Datos identificativos

    Identificador: imarina:9287716
    Autores:
    Moeen, SawairaIkram, MuhammadHaider, AliHaider, JunaidUl-Hamid, AnwarNabgan, WalidShujah, TahiraNaz, MisbahShahzadi, Iram
    Resumen:
    The present study demonstrates the hydrothermal synthesis of SnO2 quantum dots (QDs) doped with different concentrations (2, 4 wt %) of magnesium (Mg) and a fixed amount of chitosan (CS). The obtained samples were investigated through a number of characterizations for optical analysis, elemental composition, crystal structure, functional group presence, interlayer spacing, and surface morphology. The XRD spectrum revealed the tetragonal structure of SnO2 with no significant variations occurring upon the addition of CS and Mg. The crystallite size of QDs was reduced by incorporation of dopants. The optical absorption spectra revealed a red shift, assigned to the reduction of the band gap energy upon doping. TEM analysis proved that the few nanorod-like structures of CS overlapped with SnO2 QDs, and agglomeration was observed upon Mg doping. The incorporation of dopants little enhanced the d-spacing of SnO2 QDs. Moreover, the synthesized nanocatalyst was utilized to calculate the degradation percentage of methylene blue (MB) dye. Afterward, a comparative analysis of catalytic activity, photocatalytic activity, and sonophotocatalytic activity was carried out. Notably, 4% Mg/CS-doped QDs showed maximum sonophotocatalytic degradation of MB in basic medium compared to other activities. Lastly, the prepared nanocatalyst was found to be efficient for dye degradation in any environment and inexpensive.
  • Otros:

    Autor según el artículo: Moeen, Sawaira; Ikram, Muhammad; Haider, Ali; Haider, Junaid; Ul-Hamid, Anwar; Nabgan, Walid; Shujah, Tahira; Naz, Misbah; Shahzadi, Iram;
    Departamento: Enginyeria Química
    Autor/es de la URV: Nabgan, Walid
    Palabras clave: Zno Sno2 Sensor Pure Optical-properties Molecular docking analysis Dye degradation Bactericidal behavior
    Resumen: The present study demonstrates the hydrothermal synthesis of SnO2 quantum dots (QDs) doped with different concentrations (2, 4 wt %) of magnesium (Mg) and a fixed amount of chitosan (CS). The obtained samples were investigated through a number of characterizations for optical analysis, elemental composition, crystal structure, functional group presence, interlayer spacing, and surface morphology. The XRD spectrum revealed the tetragonal structure of SnO2 with no significant variations occurring upon the addition of CS and Mg. The crystallite size of QDs was reduced by incorporation of dopants. The optical absorption spectra revealed a red shift, assigned to the reduction of the band gap energy upon doping. TEM analysis proved that the few nanorod-like structures of CS overlapped with SnO2 QDs, and agglomeration was observed upon Mg doping. The incorporation of dopants little enhanced the d-spacing of SnO2 QDs. Moreover, the synthesized nanocatalyst was utilized to calculate the degradation percentage of methylene blue (MB) dye. Afterward, a comparative analysis of catalytic activity, photocatalytic activity, and sonophotocatalytic activity was carried out. Notably, 4% Mg/CS-doped QDs showed maximum sonophotocatalytic degradation of MB in basic medium compared to other activities. Lastly, the prepared nanocatalyst was found to be efficient for dye degradation in any environment and inexpensive.
    Áreas temáticas: Química Interdisciplinar General chemistry General chemical engineering Engenharias ii Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemical engineering (miscellaneous) Chemical engineering (all)
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: walid.nabgan@urv.cat
    Identificador del autor: 0000-0001-9901-862X
    Fecha de alta del registro: 2024-09-07
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original: https://pubs.acs.org/doi/10.1021/acsomega.2c05133
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Acs Omega. 7 (50): 46428-46439
    Referencia de l'ítem segons les normes APA: Moeen, Sawaira; Ikram, Muhammad; Haider, Ali; Haider, Junaid; Ul-Hamid, Anwar; Nabgan, Walid; Shujah, Tahira; Naz, Misbah; Shahzadi, Iram; (2022). Comparative Study of Sonophotocatalytic, Photocatalytic, and Catalytic Activities of Magnesium and Chitosan-Doped Tin Oxide Quantum Dots. Acs Omega, 7(50), 46428-46439. DOI: 10.1021/acsomega.2c05133
    DOI del artículo: 10.1021/acsomega.2c05133
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2022
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Chemical Engineering (Miscellaneous),Chemistry (Miscellaneous),Chemistry, Multidisciplinary
    Zno
    Sno2
    Sensor
    Pure
    Optical-properties
    Molecular docking analysis
    Dye degradation
    Bactericidal behavior
    Química
    Interdisciplinar
    General chemistry
    General chemical engineering
    Engenharias ii
    Ciências agrárias i
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemical engineering (miscellaneous)
    Chemical engineering (all)
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