Autor según el artículo: Fellah, I; Djellabi, R; Ben Amor, H; Hamdi, N; Ordonez, MF; Bianchi, CL
Departamento: Enginyeria Química
Autor/es de la URV: Djellabi, Ridha
Palabras clave: Water treatment Tio -smectite 2 Solar photocatalysis Shuttle Adsorb & Hdtma modification
Resumen: Slow kinetics is one of the capital issues of photocatalytic technology because of its heterogeneous nature, which involves multi-step processes. Herein, we show that the simple modification of the sol-gel-based TiO2-smectite composite by hexadecyltrimethylammonium bromide (HDTMA) significantly boosts adsorption and photocatalytic efficient sol-gel-based light towards the removal of diclofenac from water. Three photocatalysts were prepared, including TiO2, TiO2-smectite, and HDTMA-TiO2-smectite. The materials were characterized to understand the surface interaction and crystal characteristics. In terms of photoactivity, it was found that the addition of HDTMA to TiO2-smectite improved the removal rate by twice. HDTMA changes the functional groups to TiO2-smectite composite allowing enhanced adsorption and photoactivity through the so-called Adsorb and Shuttle process. The recycling tests show that HDTMA-TiO2-smectite can be used up to four times with good performance. This modification approach could intensify the removal of pollutants from water instead of using complicated and costly techniques.
Áreas temáticas: Química Physical and theoretical chemistry Farmacia Environmental science (all) Engenharias ii Ciências biológicas ii Chemistry, physical Catalysis Astronomia / física
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
Direcció de correo del autor: ridha.djellabi@urv.cat
Identificador del autor: 0000-0002-1475-5565
Fecha de alta del registro: 2024-08-03
Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
Enlace a la fuente original: https://www.mdpi.com/2073-4344/13/1/51
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Catalysts. 13 (1):
Referencia de l'ítem segons les normes APA: Fellah, I; Djellabi, R; Ben Amor, H; Hamdi, N; Ordonez, MF; Bianchi, CL (2023). Enhanced Photocatalytic Kinetics Using HDTMA Coated TiO2-Smectite Composite for the Oxidation of Diclofenac under Solar Light. Catalysts, 13(1), -. DOI: 10.3390/catal13010051
DOI del artículo: 10.3390/catal13010051
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2023
Tipo de publicación: Journal Publications