Tesis doctorals> Departament de Química

Catalytic activation of diboron reagents towards their addition to alkenes: experimental and theoretical approach

  • Identification data

    Identifier: TDX:1145
    Handle: https://hdl.handle.net/20.500.11797/TDX1145
    Authors:
    Pubill Ulldemolins, Cristina
    Abstract:
    The organoborane products are highly used in a broad number of fields, from their use in medicine as a 10B carrier for neutron capture therapy, or other molecules with biological activity, to their use as functional molecules such as polymers. Importantly, organoboranes are very versatile and powerful intermediates in the synthesis of high value products. This thesis focuses on the development of novel methodologies for catalytic boron addition to alkenes, with particular attention to the understanding of the activation mode of the diboron reagent and the mechanism of their addition to olefins. For this purpose NMR studies together with DFT (Density Functional Theory) calculations are carried out.

  • Others:

    Date: 2012-12-17
    Departament/Institute: Departament de Química Física i Inorgànica Universitat Rovira i Virgili.
    Language: eng
    Identifier: http://hdl.handle.net/10803/97206
    Source: TDX (Tesis Doctorals en Xarxa)
    Author: Pubill Ulldemolins, Cristina
    Director: Bo Jané, Carles Fernández Gutiérrez, Mª Elena
    Format: application/pdf 244 p.
    Publisher: Universitat Rovira i Virgili
    Keywords: DFT Mechanisms Boron addition Catalysis Orgaroboranes
    Title: Catalytic activation of diboron reagents towards their addition to alkenes: experimental and theoretical approach
    Subject: 547 - Química orgànica 546 - Química inorgànica 54 - Química

  • Keywords:

    547 - Química orgànica
    546 - Química inorgànica
    54 - Química

  • Documents:

    Memoria

  • Cerca a google

    Search to google scholar