New catalytic advanced oxidation processes for wastewater treatment

Identificador:  TDX:938

Handle: https://hdl.handle.net/20.500.11797/TDX938

Autores:  Yalfani, Mohammad Sadegh

Resumen:
Regarding to the improvement of Advanced Oxidation Processes for wastewater treatment, new catalytic Fenton process and catalytic ozonation were designed and studied in the removal of organic pollutants from water. Fenton process was performed using in situ generated hydrogen peroxide, which was produced from formic acid and oxygen over alumina-supported palladium catalyst. Then, the system was fully heterogenized by using bimetallic Pd-Fe catalyst and applied successfully for different categories of organic pollutants. The combination of the above oxidation process with hydrodechlorination led to high efficiency in the degradation of chlorophenols. The performance of different hydrogen substitutes in the Fenton process using in situ generated hydrogen peroxide showed higher efficiency of hydroxylamine for neutral solutions. Concerning the development of new catalytic materials for catalytic ozonation, the degradation of pharmaceutical compounds was performed using dawsonite-derived copper catalysts. The copper incorporated into the structure of dawsonite indicated higher activity in catalytic ozonation with respect to the calcined sample, soluble copper and aluminasupported copper oxide.