Synthesis and characterization of peri-naphthalene derivatives

Identifier:  TFG:306

Handle: https://hdl.handle.net/20.500.11797/TFG306

Authors:  Royes Buisán, Jordi

Abstract:
The Peri-naphthalenes was proved that is a molecular skeleton which is extremely useful for studying the interaction between electrophile and nucleophile groups, and in this form has the chance to study the behaviours of those, in close proximity. So in this project, it was tried to focus the attention on the possible interactions between a boron group with different substituents in a close proximity in the peri-positions such as a double or triple bond carbon-carbon. It was tried also to look at the interactions between a double bond with a carbonyl group. None has studied until this moment this type of interaction at boron or carbonyl with double or triple bonds in relative peri-positions. Successful results to obtain the target molecules have not been reached yet and try to analyse with X-Ray crystallography has not been possible to do. Nevertheless, a lot of chemistry has been done, various routes for prepare the target molecules have been investigated. The research carried in this project is important for the next studies in this area, to try to obtain the target molecules and observe the behaviour between this two groups.