Entity: Universitat Rovira i Virgili (URV)
Confidenciality: No
Education area(s): Síntesi, Catàlisi i Disseny Molecular
Title in different languages: Transborylation reaction of alkenyl boranes with diboron reagents and gem-diboryl alkanes
Abstract: Exchange of boryl moieties between alkenyl boranes and diboron reagents has been postulated as a cross-metathesis pathway with concomitant formation of mixed diboron reagents. The stereocontrol of the sequence is guaranteed throughout the transborylation methodology. Herein, we describe the synthesis and characterization of different types of transborylated products. Finally, preliminary studies on the transborylation reaction between alkenyl boranes and gem-diboryl alkanes, with the subsequent formation of mixed unsymmetrical gem-diboryl alkanes, are disclosed
Subject: Química
Academic year: 2020-2021
Language: en
Work's public defense date: 2021-05-25
Subject areas: Chemistry
Student: Dominguez Molano, Paula
Department: Química Física i Inorgànica
Creation date in repository: 2022-06-21
Keywords: chemistry, alkenyl, boranes, transborilation, organic synthesis
Title in original language: Transborylation reaction of alkenyl boranes with diboron reagents and gem-diboryl alkanes
Access Rights: info:eu-repo/semantics/openAccess
Project director: Fernández Gutiérrez, Elena
Repositori URV