Autor segons l'article: A. Serra; O. Korychenska; C. Acebo; M. Bezuglyi; J.V. Grazulevicius
Departament: Química Analítica i Química Orgànica
Autor/s de la URV: SERRA ALBET, MARIA ANGELS; O. Korychenska; C. Acebo; M. Bezuglyi; J.V. Grazulevicius
Paraules clau: epoxy resins hyperbranched polymers Thermosets
Resum: New epoxy-thiol thermosets containing carbazolyl moieties were prepared by adding different proportions of a hyperbranched poly(ethyleneimine) with carbazolyl terminated units to diglycidylether of bisphenol A/trimethylolpropane tris(3-mercaptopropionate) stoichiometric formulations. This carbazolyl decorated hyperbranched polymer was synthesized from commercially available hyperbranched poly(ethyleneimine) and N-glycidyl carbazole and was characterized by standard procedures.
The influence of adding different proportions of the modifier to the formulation on the curing process was determined by calorimetry after the selection of the most adequate latent initiator, which was a urethane compound, named PDU-250. Its decomposition at a well-defined temperature liberates the amine that initiates the thiol-epoxy curing process.
The materials obtained with different proportions of modifier were characterized by means of thermomechanical analysis. On increasing the proportion of modifier, the glass transition temperature and the damping characteristics increased, but the thermal stability and the homogeneity were reduced.
The films obtained by curing the different formulations exhibited fluorescence maxima at 370–374 nm. The fluorescence quantum yields were in the range of 17–32% and they decreased with the increase of the amount of the modifier in the materials.
Grup de recerca: Polimers
Àrees temàtiques: Química Química Chemistry
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1381-5148
Identificador de l'autor: n/a; n/a; n/a; n/a; n/a
Data d'alta del registre: 2016-09-13
Pàgina final: 92
Volum de revista: 106
Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion
Enllaç font original: https://www.sciencedirect.com/science/article/abs/pii/S1381514816301432?via%3Dihub
DOI de l'article: 10.1016/j.reactfunctpolym.2016.07.012
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2016
Pàgina inicial: 86
Tipus de publicació: Article Artículo Article
Repositori URV