Articles producció científica> Química Analítica i Química Orgànica

Phenomenological characterization of sequential dual-curing of off-stoichiometric "thiol-epoxy" systems: Towards applicability

  • Dades identificatives

    Identificador: PC:1936
    Autors:
    Silvia De la FlorAlberto BelmonteXavier Fernández-FrancosÀngels Serra
    Resum:
    Filiació URV: SIInclòs a la memòria: SI
  • Altres:

    Autor segons l'article: Silvia De la Flor; Alberto Belmonte; Xavier Fernández-Francos; Àngels Serra
    Departament: Química Analítica i Química Orgànica Enginyeria Mecànica
    Autor/s de la URV: DE LA FLOR LOPEZ, SILVIA; Alberto Belmonte; Xavier Fernández-Francos; Àngels Serra
    Paraules clau: Dual-curing Rheological analysis Thiol-epoxy
    Resum: An extensive characterization of a sequential dual-curing system based on off-stoichiometric “thiol-epoxy” mixtures was carried out using thiol compounds of different functionality. The intermediate and final materials obtained after each curing stages at different thiol-epoxy ratios were studied by means of thermomechanical and rheological experiments. The storage and loss modulus and the loss factor tan δ were monitored during the curing process to analyse gelation and network structure build-up. The critical ratio for gelation was determined making use of the ideal Flory-Stockmayer theory and compared with experimental results. Intermediate materials obtained in the vicinity of the theoretical critical ratio did not have the mechanical consistency expected for partially crosslinked materials, did not retain their shape and even experienced undesired flow upon heating to activate the second curing reaction. The rheological results showed that the critical ratio is higher than the predicted value and that a softening during the second curing stage affects the shape-retention at this ratio. From the thermomechanical results, a wide range of intermediate and final materials with different properties and applicability can be obtained by properly choosing the thiol-epoxy ratio: from liquid-like to highly deformable intermediate materials and from moderately crosslinked (deformable) to highly crosslinked (brittle) final materials.
    Grup de recerca: Grup d'Investigació en Enginyeria Computacional i Experimental
    Àrees temàtiques: Enginyeria mecànica Ingeniería mecánica Mechanical engineering
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 0261-3069
    Identificador de l'autor: 0000-0002-6851-1371; n/a; 0000-0002-3492-2922; 0000-0003-1387-0358
    Data d'alta del registre: 2016-11-02
    Pàgina final: 127
    Volum de revista: 113
    Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion
    Enllaç font original: https://www.sciencedirect.com/science/article/abs/pii/S0264127516313004?via%3Dihub
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    DOI de l'article: 10.1016/j.matdes.2016.10.009
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2017
    Pàgina inicial: 116
    Tipus de publicació: Article Artículo Article
  • Paraules clau:

    Tiols
    Dual-curing
    Rheological analysis
    Thiol-epoxy
    Enginyeria mecànica
    Ingeniería mecánica
    Mechanical engineering
    0261-3069
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