Articles producció científica> Enginyeria Química

Hydrolysis of dilute acid-pretreated cellulose under mild hydrothermal conditions

  • Dades identificatives

    Identificador: PC:743
    Autors:
    Chimentão, R.J.Lorente, E.Gispert-Guirado, F.Medina, F.López, F.
    Resum:
    10.1016/j.carbpol.2014.04.001
  • Altres:

    Autor segons l'article: Chimentão, R.J. Lorente, E. Gispert-Guirado, F. Medina, F. López, F.
    Departament: Enginyeria Química
    Resum: The hydrolysis of dilute acid-pretreated cellulose was investigated in a conventional oven and under microwave heating. Two acids - sulfuric and oxalic - were studied. For both hydrothermal conditions (oven and microwave) the resultant total organic carbon (TOC) values obtained by the hydrolysis of the cellulose pretreated with sulfuric acid were higher than those obtained by the hydrolysis of the cellulose pretreated with oxalic acid. However, the dicarboxylic acid exhibited higher hydrolytic efficiency towards glucose. The hydrolysis of cellulose was greatly promoted by microwave heating. The Rietveld method was applied to fit the X-ray patterns of the resultant cellulose after hydrolysis. Oxalic acid preferentially removed the amorphous region of the cellulose and left the crystalline region untouched. On the other hand, sulfuric acid treatment decreased the ordering of the cellulose by partially disrupting its crystalline structure.
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 0008-6215
    Pàgina final: 124
    Volum de revista: 111
    Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion
    Enllaç font original: http://www.sciencedirect.com/science/article/pii/S0144861714003506
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    DOI de l'article: 10.1016/j.carbpol.2014.04.001
    Entitat: Universitat Rovira i Virgili.
    Any de publicació de la revista: 2014
    Pàgina inicial: 116