Articles producció científica> Química Analítica i Química Orgànica

Gold carbene or carbenoid: Is there a difference?

  • Dades identificatives

    Identificador: imarina:3644050
    Handle: https://hdl.handle.net/20.500.11797/imarina3644050
    Autors:
    Wang Y, Muratore ME, Echavarren AM.
    Resum:
    Abstract By reviewing the recent progress on the elucidation of the structure of gold carbenes and the definitions of metal carbenes and carbenoids, we recommend to use the term gold carbene to describe gold carbene-like intermediates, regardless of whether the carbene or carbocation extreme resonance dominates. Gold carbenes, because of the weak metal-to-carbene ¿-back-donation and their strongly electrophilic reactivity, could be classified into the broader family of Fischer carbenes, although their behavior and properties are very specific. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  • Altres:

    Autor segons l'article: Wang Y, Muratore ME, Echavarren AM.
    Departament: Química Analítica i Química Orgànica
    Autor/s de la URV: ECHAVARREN PABLOS, ANTONIO
    Paraules clau: Gold Fischer carbenes Carbocations Carbenoids Carbenes Back donation fischer carbenes carbocations carbenoids carbenes
    Resum: Abstract By reviewing the recent progress on the elucidation of the structure of gold carbenes and the definitions of metal carbenes and carbenoids, we recommend to use the term gold carbene to describe gold carbene-like intermediates, regardless of whether the carbene or carbocation extreme resonance dominates. Gold carbenes, because of the weak metal-to-carbene ¿-back-donation and their strongly electrophilic reactivity, could be classified into the broader family of Fischer carbenes, although their behavior and properties are very specific. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
    Àrees temàtiques: Química Organic chemistry Medicina i Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iii Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Catalysis Biotecnología Biodiversidade Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    Adreça de correu electrònic de l'autor: antoniomaria.echavarren@urv.cat
    Identificador de l'autor: 0000-0002-6418-7930
    Data d'alta del registre: 2024-09-07
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: Chemistry-A European Journal. 21 (20): 7332-7339
    Referència de l'ítem segons les normes APA: Wang Y, Muratore ME, Echavarren AM. (2015). Gold carbene or carbenoid: Is there a difference?. Chemistry-A European Journal, 21(20), 7332-7339. DOI: 10.1002/chem.201406318
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2015
    Tipus de publicació: Journal Publications

  • Paraules clau:

    Catalysis,Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary,Organic Chemistry
    Gold
    Fischer carbenes
    Carbocations
    Carbenoids
    Carbenes
    Back donation
    fischer carbenes
    carbocations
    carbenoids
    carbenes
    Química
    Organic chemistry
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias iii
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Catalysis
    Biotecnología
    Biodiversidade
    Astronomia / física

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